Chapter 15: Problem 43
Cite four factors that determine what fabrication technique is used to form polymeric materials.
Chapter 15: Problem 43
Cite four factors that determine what fabrication technique is used to form polymeric materials.
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Get started for freeThe vulcanization of polyisoprene is accomplished with sulfur atoms according to Equation 15.4. If \(57 \mathrm{wt} \%\) sulfur is combined with polyisoprene, how many crosslinks will be associated with each isoprene repeat unit if it is assumed that, on the average, six sulfur atoms participate in each crosslink?
Briefly explain how each of the following influences the tensile or yield strength of a semicrystalline polymer and why: (a) Molecular weight (b) Degree of crystallinity (c) Deformation by drawing (d) Annealing of an undeformed material
For some viscoelastic polymers that are subjected to stress relaxation tests, the stress decays with time according to $$ \sigma(t)=\sigma(0) \exp \left(-\frac{t}{\tau}\right) $$ where \(\sigma(t)\) and \(\sigma(0)\) represent the timedependent and initial (i.e., time \(=0\) ) stresses, respectively, and \(t\) and \(\tau\) denote elapsed time and the relaxation time; \(\tau\) is a timeindependent constant characteristic of the material. A specimen of a viscoelastic polymer whose stress relaxation obeys Equation \(15.10\) was suddenly pulled in tension to a measured strain of \(0.6\); the stress necessary to maintain this constant strain was measured as a function of time. Determine \(E_{r}(10)\) for this material if the initial stress level was \(2.76\) MPa (400 psi), which dropped to \(1.72 \mathrm{MPa}\) (250 psi) after \(60 \mathrm{~s}\).
List two important characteristics for polymers that are to be used in fiber applications.
Contrast compression, injection, and transfer molding techniques that are used to form plastic materials.
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