Chapter 15: Problem 46
Which of the following polyethylene thin films would have the better mechanical characteristics: (1) formed by blowing, or (2) formed by extrusion and then rolled? Why?
Chapter 15: Problem 46
Which of the following polyethylene thin films would have the better mechanical characteristics: (1) formed by blowing, or (2) formed by extrusion and then rolled? Why?
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The vulcanization of polyisoprene is accomplished with sulfur atoms according to Equation 15.4. If \(57 \mathrm{wt} \%\) sulfur is combined with polyisoprene, how many crosslinks will be associated with each isoprene repeat unit if it is assumed that, on the average, six sulfur atoms participate in each crosslink?
On the basis of the curves in Figure \(15.5\), sketch schematic strain-time plots for the following polystyrene materials at the specified temperatures: (a) Crystalline at \(70^{\circ} \mathrm{C}\) (b) Amorphous at \(180^{\circ} \mathrm{C}\) (c) Crosslinked at \(180^{\circ} \mathrm{C}\) (d) Amorphous at \(100^{\circ} \mathrm{C}\).
Briefly explain the difference in molecular chemistry between silicone polymers and other polymeric materials.
For each of the following pairs of polymers, plot and label schematic stress- strain curves on the same graph [i.e., make separate plots for parts (a), (b), and (c)] (a) Isotactic and linear polypropylene havng a weight-average molecular weight of \(120,000 \mathrm{~g} / \mathrm{mol}\); atactic and linear polypropyene having a weight-average molecular weight of \(100,000 \mathrm{~g} / \mathrm{mol}\) (b) Branched poly(vinyl chloride) having a degree of polymerization of 2000 ; heavily crosslinked poly(vinyl chloride) having a degree of polymerization of 2000 (c) Poly(styrene-butadiene) random copolymer having a number-average molecular weight of \(100,000 \mathrm{~g} / \mathrm{mol}\) and \(10 \%\) of the available sites crosslinked and tested at \(20^{\circ} \mathrm{C}\); poly(styrene- butadiene) random copolymer having a number-average molecular weight of \(120,000 \mathrm{~g} / \mathrm{mol}\) and \(15 \%\) of the available sites crosslinked and tested at \(-85^{\circ} \mathrm{C}\). Hint: poly(styrene- butadiene) copolymers may exhibit elastomeric behavior.
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