Chapter 15: Problem 5
In your own words, briefly describe the phenomenon of viscoelasticity.
Chapter 15: Problem 5
In your own words, briefly describe the phenomenon of viscoelasticity.
All the tools & learning materials you need for study success - in one app.
Get started for free(a) Compare the fatigue limits for polystyrene (Figure 15.11) and the cast iron for which fatigue data are given in Problem 8.20. (b) Compare the fatigue strengths at \(10^{6} \mathrm{cy}\) cles for poly(ethylene terephthalate) (PET, Figure 15.11) and red brass (Figure 8.34).
For each of the following pairs of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if his is possible, note which has the higher ensile modulus and then cite the reason(s) or your choice; and (3) if it is not possible o decide, then state why. a) Random acrylonitrile-butadiene copolyner with \(10 \%\) of possible sites crosslinked; ilternating acrylonitrile-butadiene copolymer with \(5 \%\) of possible sites crosslinked (b) Branched and syndiotactic polypropylene with a degree of polymerization of 5000 ; linear and isotactic polypropylene with a degree of polymerization of 3000 (c) Branched polyethylene with a numberaverage molecular weight of \(250,000 \mathrm{~g} / \mathrm{mol}\); linear and isotactic poly(vinyl chloride) with a number-average molecular weight of \(200,000 \mathrm{~g} / \mathrm{mol}\)
For some viscoelastic polymers that are subjected to stress relaxation tests, the stress decays with time according to $$ \sigma(t)=\sigma(0) \exp \left(-\frac{t}{\tau}\right) $$ where \(\sigma(t)\) and \(\sigma(0)\) represent the timedependent and initial (i.e., time \(=0\) ) stresses, respectively, and \(t\) and \(\tau\) denote elapsed time and the relaxation time; \(\tau\) is a timeindependent constant characteristic of the material. A specimen of a viscoelastic polymer whose stress relaxation obeys Equation \(15.10\) was suddenly pulled in tension to a measured strain of \(0.6\); the stress necessary to maintain this constant strain was measured as a function of time. Determine \(E_{r}(10)\) for this material if the initial stress level was \(2.76\) MPa (400 psi), which dropped to \(1.72 \mathrm{MPa}\) (250 psi) after \(60 \mathrm{~s}\).
Why must fiber materials that are melt-spun and then drawn be thermoplastic? Cite two reasons.
On the basis of the curves in Figure \(15.5\), sketch schematic strain-time plots for the following polystyrene materials at the specified temperatures: (a) Crystalline at \(70^{\circ} \mathrm{C}\) (b) Amorphous at \(180^{\circ} \mathrm{C}\) (c) Crosslinked at \(180^{\circ} \mathrm{C}\) (d) Amorphous at \(100^{\circ} \mathrm{C}\).
What do you think about this solution?
We value your feedback to improve our textbook solutions.