Chapter 17: Problem 20
Briefly describe the phenomenon of passivity. Name two common types of alloy that passivate.
Chapter 17: Problem 20
Briefly describe the phenomenon of passivity. Name two common types of alloy that passivate.
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Get started for freeBriefly describe the two techniques that are used for galvanic protection. Oxidation.
(a) Demonstrate that the CPR is related to the corrosion current density \(i\left(\mathrm{~A} / \mathrm{cm}^{2}\right)\), through the expression $$ \mathrm{CPR}=\frac{K A i}{n \rho} $$ where \(K\) is a constant, \(A\) is the atomic weight of the metal experiencing corrosion, \(n\) is the number of electrons associated with the ionization of each metal atom, and \(\rho\) is the density of the metal. (b) Calculate the value of the constant \(K\) for the \(\mathrm{CPR}\) in \(\mathrm{mpy}\) and \(i\) in \(\mu \mathrm{A} / \mathrm{cm}^{2}\left(10^{-6}\right.\) \(\left.\mathrm{A} / \mathrm{cm}^{2}\right)\)
(a) What are inhibitors? (b) What possible mechanisms account for their effectiveness?
For the following pairs of alloys that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode. (a) Aluminum and magnesium (b) Zinc and a low-carbon steel (c) Brass ( \(60 \mathrm{wt} \% \mathrm{Cu}-40 \mathrm{wt} \% \mathrm{Zn}\) ) and Monel \((70 \mathrm{wt} \% \mathrm{Ni}-30 \mathrm{wt} \% \mathrm{Cu})\) (d) Titanium and 304 stainless steel (e) Cast iron and 316 stainless steel
(a) Write the possible oxidation and reduction half-reactions that occur when magnesium is immersed in each of the following solutions: (i) HCl, (ii) an HCl solution containing dissolved oxygen, and (iii) an HCl solution containing dissolved oxygen and, in addition, \(\mathrm{Fe}^{2+}\) ions. (b) In which of these solutions would you expect the magnesium to oxidize most rapidly? Why?
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