Briefly describe the phenomenon of passivity. Name two common types of alloy that passivate.

Short Answer

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Answer: Passivity is a phenomenon observed in certain metals and alloys where they form a protective oxide layer on their surface under specific environmental conditions. This oxide layer serves as a barrier, preventing further oxidation or corrosion. Two common alloys that exhibit passivity are stainless steel and aluminum alloys. Stainless steel contains chromium, which reacts with oxygen to form a protective chromium oxide layer, while aluminum alloys develop an aluminum oxide layer on their surface when exposed to the atmosphere. Both of these oxide layers provide excellent corrosion resistance.

Step by step solution

01

Define Passivity

Passivity is a phenomenon seen in certain metals and alloys in which, under specific environmental conditions, they tend to form a protective oxide layer on their surface. This oxide layer acts as a barrier, preventing further oxidation or corrosion of the metal. This is a useful property for metals and alloys used in harsh environments, as it helps to prolong their lifespan.
02

Describe the Process of Passivation

The process of passivation occurs naturally in some metals and alloys. When these materials come in contact with corrosive environments such as air, water, or chemical substances, they react with these environments and form an oxide layer on their surface. This oxide layer is usually very thin (in the order of few nanometers) but impervious to further corrosive attack, thereby protecting the metal or alloy beneath.
03

Explain the Importance of Passivity

The ability of a metal or alloy to passivate is important for various applications. Passivity is particularly valuable for materials used in environments where corrosion is a major concern, such as in the construction, transportation, and energy industries. The passivity phenomenon helps these materials to maintain their strength and integrity, improving both their life span and performance.
04

Name Two Common Types of Alloy that Passivate

Two common types of alloys that exhibit passivity are: 1. Stainless Steel: This is an alloy of iron, chromium, nickel, and other elements. The chromium in the alloy reacts with oxygen in the environment to form a thin chromium oxide layer on the surface of the steel. This oxide layer is stable, adherent, and acts as a barrier to further oxidation or corrosion, giving stainless steel its excellent resistance to corrosion. 2. Aluminum Alloys: Aluminum alloys are lightweight materials with a high strength-to-weight ratio, making them attractive for various applications. When exposed to the atmosphere, aluminum forms a thin layer of aluminum oxide on its surface, which adheres to the metal and provides a barrier against further oxidation or corrosion, contributing to its excellent corrosion resistance.

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Most popular questions from this chapter

Briefly describe the two techniques that are used for galvanic protection. Oxidation.

(a) Demonstrate that the CPR is related to the corrosion current density \(i\left(\mathrm{~A} / \mathrm{cm}^{2}\right)\), through the expression $$ \mathrm{CPR}=\frac{K A i}{n \rho} $$ where \(K\) is a constant, \(A\) is the atomic weight of the metal experiencing corrosion, \(n\) is the number of electrons associated with the ionization of each metal atom, and \(\rho\) is the density of the metal. (b) Calculate the value of the constant \(K\) for the \(\mathrm{CPR}\) in \(\mathrm{mpy}\) and \(i\) in \(\mu \mathrm{A} / \mathrm{cm}^{2}\left(10^{-6}\right.\) \(\left.\mathrm{A} / \mathrm{cm}^{2}\right)\)

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