or each form of corrosion, other than uniform, do the following: (a) Describe why, where, and the conditions under which the corrosion occurs. (b) Cite three measures that may be taken to prevent or control it.

Short Answer

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Short Answer: Three forms of corrosion other than uniform corrosion are pitting corrosion, crevice corrosion, and galvanic corrosion. Pitting corrosion involves localized cavities or holes on metal surfaces and occurs in materials exposed to corrosive substances. Crevice corrosion happens in tight spaces where corrosive substances are trapped and oxygen levels differ from the external environment. Galvanic corrosion takes place when two dissimilar metals are connected, causing the less noble metal to corrode and protect the other. Preventive measures include using corrosion-resistant materials, applying protective coatings, controlling the environment, improving design, isolating dissimilar metals, and introducing cathodic protection.

Step by step solution

01

1. Pitting Corrosion

Pitting corrosion is a localized form of corrosion in which small cavities or holes form on the metal surface due to a breakdown of its protective layer. It generally occurs in materials exposed to flow of corrosive substances, such as chloride ions or stagnant water with high salt content. Pitting can lead to equipment failure, as it weakens the metal structure internally.
02

Preventive Measures for Pitting Corrosion

(a) Use materials with enhanced corrosion resistance, such as stainless steel or alloying elements that can form a passive oxide film on the surface. (b) Apply protective coatings or linings to the metal surface to prevent direct contact with corrosive substances. (c) Control the environment by removing or reducing corrosive substances, maintaining proper pH levels, and controlling temperature.
03

2. Crevice Corrosion

Crevice corrosion occurs in localized areas where tight spaces or crevices are present, such as between fasteners, gaskets, or flanges. These small spaces can trap corrosive substances, creating a different environment than the rest of the material's surface. As the oxygen levels are reduced inside a crevice compared to the external environment, a differential aeration cell is created, which leads to selective corrosion inside the crevice.
04

Preventive Measures for Crevice Corrosion

(a) Eliminate or minimize crevices in design, such as using continuous welds in place of bolts or rivets. (b) Apply protective coatings or use sealants or gaskets made of non-absorbent, corrosion-resistant materials. (c) Regularly inspect and clean crevices to remove any deposits or substances that may cause corrosion.
05

3. Galvanic Corrosion

Galvanic corrosion occurs when two dissimilar metals are connected in an electrolyte, forming an electrochemical cell. The less noble metal, or the one with lower electrochemical potential, will corrode in preference to the other, protecting it from corrosion. This type of corrosion is common in structures where multiple metals are in contact, such as piping systems, structural elements, and electronic connectors.
06

Preventive Measures for Galvanic Corrosion

(a) Use compatible materials, which are closer in electrochemical potential or select materials with similar corrosion characteristics. (b) Isolate dissimilar metals with insulation materials, coatings, or separators to prevent direct contact. (c) Introduce cathodic protection, such as sacrificial anodes or a direct electrical current, to protect the vulnerable metal by effectively making it a cathode in the electrochemical cell. By understanding these corrosion mechanisms and implementing appropriate preventive measures, the detrimental effects of corrosion can be mitigated in various industrial and engineering applications.

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Most popular questions from this chapter

Briefly describe the two techniques that are used for galvanic protection. Oxidation.

For each of the metals listed in the following table, compute the Pilling- Bedworth ratio. Also, on the basis of this value, specify whether you would expect the oxide scale that forms on the surface to be protective, and then justify your decision. Density data for both the metal and its oxide are also tabulated. \begin{tabular}{lccc} \hline & Metal Metal & Density \(\left(\mathrm{g} / \mathrm{cm}^{3}\right)\) & Metal Oxide & Oxide Density \(\left(\mathrm{g} / \mathrm{cm}^{\mathbf{7}}\right)\) \\ \hline \(\mathrm{Zr}\) & \(6.51\) & \(\mathrm{ZrO}_{2}\) & \(5.89\) \\ \(\mathrm{Sn}\) & \(7.30\) & \(\mathrm{SnO}_{2}\) & \(6.95\) \\ \(\mathrm{Bi}\) & \(9.80\) & \(\mathrm{Bi}_{2} \mathrm{O}_{3}\) & \(8.90\) \\ \hline \end{tabular}

An electrochemical cell is composed of pure copper and pure lead electrodes immersed in solutions of their respective divalent ions. For a \(0.6 M\) concentration of \(\mathrm{Cu}^{2+}\), the lead electrode is oxidized, yielding a cell potential of \(0.507 \mathrm{~V} .\) Calculate the concentration of \(\mathrm{Pb}^{2+}\) ions if the temperature is \(25^{\circ} \mathrm{C}\).

(a) From the galvanic series (Table 17.2), cite three metals or alloys that may be used to galvanically protect 304 stainless steel in the active state. (b) As Concept Check 17.4(b) notes, galvanic corrosion is prevented by making an electrical contact between the two metals in the couple and a third metal that is anodic to the other two. Using the galvanic series, name one metal that could be used to protect a copper-aluminum galvanic couple.

(a) Cite the major differences between activation and concentration polarizations. (b) Under what conditions is activation polarization rate controlling? (c) Under what conditions is concentration polarization rate controlling?

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