Chapter 2: Problem 18
(a) Briefly cite the main differences between ionic, covalent, and metallic bonding. (b) State the Pauli exclusion principle.
Chapter 2: Problem 18
(a) Briefly cite the main differences between ionic, covalent, and metallic bonding. (b) State the Pauli exclusion principle.
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Get started for free(a) Cite two important quantum-mechanical concepts associated with the Bohr model of the atom. (b) Cite two important additional refinements that resulted from the wave- mechanical atomic model.
Chromium has four naturally occurring isotopes: \(4.34 \%\) of \({ }^{50} \mathrm{Cr}\), with an atomic weight of \(49.9460\) amu; \(83.79 \%\) of \({ }^{52} \mathrm{Cr}\), with an atomic weight of \(51.9405 \mathrm{amu} ; 9.50 \%\) of \({ }^{53} \mathrm{Cr}\), with an atomic weight of \(52.9407 \mathrm{amu} ;\) and \(2.37 \%\) of \({ }^{54} \mathrm{Cr}\), with an atomic weight of \(53.9389\) amu. On the basis of these data, confirm that the average atomic weight of \(\mathrm{Cr}\) is \(51.9963 \mathrm{amu}\)
For \(\mathrm{a} \mathrm{K}^{+}-\mathrm{Cl}^{-}\)ion pair, attractive and repulsive energies \(E_{A}\) and \(E_{R}\), respectively, depend on the distance between the ions \(r\), according to $$ \begin{aligned} E_{A} &=-\frac{1.436}{r} \\ E_{R} &=\frac{5.86 \times 10^{-6}}{r^{9}} \end{aligned} $$ For these expressions, energies are expressed in electron volts per \(\mathrm{K}^{+}-\mathrm{Cl}^{-}\)pair, and \(r\) is the distance in nanometers. The net energy \(E_{N}\) is just the sum of the preceding two expressions. (a) Superimpose on a single plot \(E_{N}, E_{R}\), and \(E_{A}\) versus \(r\) up to \(1.0 \mathrm{~nm}\). (b) On the basis of this plot, determine (i) the equilibrium spacing \(r_{0}\) between the \(\mathrm{K}^{+}\)and \(\mathrm{Cl}^{-}\)ions, and (ii) the magnitude of the bonding energy \(E_{0}\) between the two ions. (c) Mathematically determine the \(r_{0}\) and \(E_{0}\) values using the solutions to Problem \(2.14\) and compare these with the graphical results from part (b).
(a) How many grams are there in one amu of a material? (b) Mole, in the context of this book, is taken in units of gram-mole. On this basis, how many atoms are there in a pound-mole of a substance?
Explain why hydrogen fluoride (HF) has a higher boiling temperature than hydrogen chloride (HCl) \(\left(19.4^{\circ} \mathrm{C}\right.\) vs. \(\left.-85^{\circ} \mathrm{C}\right)\), even though HF has a lower molecular weight.
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