Chapter 2: Problem 22
What type(s) of bonding would be expected for each of the following materials: solid xenon, calcium fluoride \(\left(\mathrm{CaF}_{2}\right),\) bronze, cadmium tel luride (CdTe), rubber, and tungsten?
Chapter 2: Problem 22
What type(s) of bonding would be expected for each of the following materials: solid xenon, calcium fluoride \(\left(\mathrm{CaF}_{2}\right),\) bronze, cadmium tel luride (CdTe), rubber, and tungsten?
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Get started for freeRelative to electrons and electron states, what does each of the four quantum numbers specify?
6 Allowed values for the quantum numbers of electrons are as follows: $$ \begin{aligned} n &=1,2,3, \ldots \\ l &=0,1,2,3, \ldots, n-1 \\ m_{l} &=0, \pm 1, \pm 2, \pm 3, \ldots, \pm l \\ m_{s} &=\pm \frac{1}{2} \end{aligned} $$ The relationships between \(n\) and the shell designations are noted in Table 2.1. Relative to the subshells, \(l=0\) corresponds to an \(s\) subshell \(l=1\) corresponds to a \(p\) subshell \(l=2\) corresponds to a \(d\) subshell \(l=3\) corresponds to an \(f\) subshell For the \(K\) shell, the four quantum numbers for each of the two electrons in the \(1 s\) state, in the order of \(n l m_{i} m_{s}\), are \(100 \frac{1}{2}\) and \(100\left(-\frac{1}{2}\right)\) Write the four quantum numbers for all of the electrons in the \(L\) and \(M\) shells, and note which correspond to the \(s, p\), and \(d\) subshells.
(a) Cite two important quantum-mechanical concepts associated with the Bohr model of the atom. (b) Cite two important additional refinements that resulted from the wave- mechanical atomic model.
With regard to electron configuration, what do all the elements in Group VIIA of the periodic table have in common?
For \(\mathrm{a} \mathrm{K}^{+}-\mathrm{Cl}^{-}\)ion pair, attractive and repulsive energies \(E_{A}\) and \(E_{R}\), respectively, depend on the distance between the ions \(r\), according to $$ \begin{aligned} E_{A} &=-\frac{1.436}{r} \\ E_{R} &=\frac{5.86 \times 10^{-6}}{r^{9}} \end{aligned} $$ For these expressions, energies are expressed in electron volts per \(\mathrm{K}^{+}-\mathrm{Cl}^{-}\)pair, and \(r\) is the distance in nanometers. The net energy \(E_{N}\) is just the sum of the preceding two expressions. (a) Superimpose on a single plot \(E_{N}, E_{R}\), and \(E_{A}\) versus \(r\) up to \(1.0 \mathrm{~nm}\). (b) On the basis of this plot, determine (i) the equilibrium spacing \(r_{0}\) between the \(\mathrm{K}^{+}\)and \(\mathrm{Cl}^{-}\)ions, and (ii) the magnitude of the bonding energy \(E_{0}\) between the two ions. (c) Mathematically determine the \(r_{0}\) and \(E_{0}\) values using the solutions to Problem \(2.14\) and compare these with the graphical results from part (b).
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