For a \(68 \mathrm{wt} \% \mathrm{Zn}-32 \mathrm{wt} \% \mathrm{Cu}\) alloy, make schematic sketches of the microstructure that would be observed for conditions of very slow cooling at the following temperatures: \(1000^{\circ} \mathrm{C}\) \(\left(1830^{\circ} \mathrm{F}\right), 760^{\circ} \mathrm{C}\left(1400^{\circ} \mathrm{F}\right), 600^{\circ} \mathrm{C}\left(1110^{\circ} \mathrm{F}\right)\), and \(400^{\circ} \mathrm{C}\left(750^{\circ} \mathrm{F}\right)\). Label all phases and indicate their approximate compositions.

Short Answer

Expert verified
Answer: At 760°C, the microstructure of a 68 wt% Zn-32 wt% Cu alloy consists of two phases - the α phase with a composition range between 38 wt% Zn and 52 wt% Zn, and the β phase with a composition range between 52 wt% Zn and 89 wt% Zn.

Step by step solution

01

Identify the appropriate phase diagram

For this problem, we must refer to the Zn-Cu phase diagram to analyze the microstructure of the alloy at different temperatures. This phase diagram can be found in various metallurgy textbooks or through online databases. Please use the phase diagram provided by the source you have in front of you.
02

Analyze the given composition and temperatures on the phase diagram

Begin by locating the 68 wt% Zn-32 wt% Cu alloy composition on the horizontal axis of the phase diagram. Then, locate the temperatures (1000°C, 760°C, 600°C, and 400°C) on the vertical axis. For each temperature, draw a horizontal line from the temperature graduation to intersect the phase boundaries related to the given alloy composition.
03

Identify the phases present at each temperature

At each intersection point or region, determine which phases are present in the alloy's microstructure. Note the phases for each temperature, as described below: - At 1000°C: One phase-present, known as the α phase with a composition between 38 wt% Zn and 72 wt% Zn. - At 760°C: Two phases present, known as the α phase and the β phase. The α phase composition is between 38 wt% Zn and 52 wt% Zn, and the β phase composition is between 52 wt% Zn and 89 wt% Zn. - At 600°C: Two phases present, known as the α phase and the β phase. The α phase composition is between 38 wt% Zn and 52 wt% Zn, and the β phase composition is between 52 wt% Zn and 89 wt% Zn. - At 400°C: One phase present, known as the β phase with a composition between 52 wt% Zn and 89 wt% Zn.
04

Make schematic sketches of the microstructure at each temperature

Based on the phase descriptions in Step 3, create schematic sketches of the alloy microstructure at each temperature: - 1000°C: Sketch a microstructure consisting only of the α phase. Label this phase and indicate its composition range (38 wt%-72 wt% Zn). - 760°C: Sketch a microstructure containing both the α and β phases. Show the α phase as a continuous matrix, and the β phase as embedded particles within the α phase. Label both phases and indicate their composition ranges (α: 38 wt%-52 wt% Zn, β: 52 wt%-89 wt% Zn). - 600°C: Sketch a microstructure containing both the α and β phases, with the β phase becoming more predominant as the temperature decreases. Label both phases and indicate their composition ranges (α: 38 wt%-52 wt% Zn, β: 52 wt%-89 wt% Zn). - 400°C: Sketch a microstructure consisting only of the β phase. Label this phase and indicate its composition range (52 wt%-89 wt% Zn). Remember that these sketches are schematic representations of the microstructure; the actual appearance may vary depending on the specific alloy and cooling conditions.

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Most popular questions from this chapter

Consider \(2.0 \mathrm{~kg}\) of a \(99.6 \mathrm{wt} \% \mathrm{Fe}-0.4 \mathrm{wt} \% \mathrm{C}\) alloy that is cooled to a temperature just below the eutectoid. (a) How many kilograms of proeutectoid ferrite form? (b) How many kilograms of eutectoid ferrite form? (c) How many kilograms of cementite form?

For alloys of two hypothetical metals \(\mathrm{A}\) and B, there exist an \(\alpha\), A-rich phase and a \(\beta\), Brich phase. From the mass fractions of both phases for two different alloys provided in the following table (which are at the same temperature), determine the composition of the phase boundary (or solubility limit) for both \(\alpha\) and \(\beta\) phases at this temperature. $$ \begin{array}{lcc} \hline \text { Alloy Composition } & \text { Fraction } & \text { Fraction } \\\ & \alpha \text { Phase } & \beta \text { Phase } \\ \hline 60 \mathrm{wt} \% \mathrm{~A}-40 \mathrm{wt} \% \text { B } & 0.57 & 0.43 \\ 30 \mathrm{wt} \% \text { A-70 wt \% B } & 0.14 & 0.86 \\ \hline \end{array} $$

A hypothetical A-B alloy of composition \(55 \mathrm{wt} \%\) B-45 \(\mathrm{wt} \% \mathrm{~A}\) at some temperature is found to consist of mass fractions of \(0.5\) for both \(\alpha\) and \(\beta\) phases. If the composition of the \(\beta\) phase is \(90 \mathrm{wt} \%\) B-10 \(\mathrm{wt} \% \mathrm{~A}\), what is the composition of the \(\alpha\) phase?

Often, the properties of multiphase alloys may be approximated by the relationship $$ E(\text { alloy })=E_{\alpha} V_{\alpha}+E_{\beta} V_{\beta} $$ where \(E\) represents a specific property (modulus of elasticity, hardness, etc.), and \(V\) is the volume fraction. The subscripts \(\alpha\) and \(\beta\) denote the existing phases or microconstituents. Employ this relationship to determine the approximate Brinell hardness of a \(99.80\) wt \% Fe-0.20 wt \% C alloy. Assume Brinell hardnesses of 80 and 280 for ferrite and pearlite, respectively, and that volume fractions may be approximated by mass fractions.

Compute the mass fractions of proeutectoid ferrite and pearlite that form in an iron-carbon alloy containing \(0.25 \mathrm{wt} \% \mathrm{C}\).

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