Chapter 12: Problem 41
Briefly answer the following: (a) Why may there be significant scatter in the fracture strength for some given ceramic material? (b) Why does fracture strength increase with de- creasing specimen size?
Chapter 12: Problem 41
Briefly answer the following: (a) Why may there be significant scatter in the fracture strength for some given ceramic material? (b) Why does fracture strength increase with de- creasing specimen size?
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Get started for freeWould you expect Frenkel defects for anions to exist in ionic ceramics in relatively large concen- trations? Why or why not?
Show that the minimum cation-to-anion radius ratio for a coordination number of 4 is 0.225.
Calculate the number of Frenkel defects per cubic meter in silver chloride at 350C. The energy for defect formation is 1.1 eV, whereas the density for AgCl is 5.50 g/cm3 at 350C.
The fracture strength of glass may be increased by etching away a thin surface layer. It is believed that the etching may alter surface crack geometry (i.e., reduce the crack length and increase the tip radius). Compute the ratio of the etched and origi- nal crack-tip radii for a fourfold increase in frac- ture strength if half of the crack length is removed.
Show that the minimum cation-to-anion radius ratio for a coordination number of 6 is 0.414. (Hint: Use the NaCl crystal structure in Figure 12.2, and assume that anions and cations are just touching along cube edges and across face diagonals.)
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