Chapter 15: Problem 38
Cite five important characteristics for polymers that are to be used in thin- film applications.
Chapter 15: Problem 38
Cite five important characteristics for polymers that are to be used in thin- film applications.
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Get started for freeWhich of the following would you expect to be (-) elastomers and which thermosetting polymers at room temperature? Justify each choice. (a) Linear and highly crystalline polyethylene (b) Phenol-formaldehyde (c) Heavily crosslinked polyisoprene having a glass transition temperature of \(50^{\circ} \mathrm{C}\left(122^{\circ} \mathrm{F}\right)\) (d) Lightly crosslinked polyisoprene having a glass transition temperature of \(-60^{\circ} \mathrm{C}\left(-76^{\circ} \mathrm{F}\right)\) (e) Linear and partially amorphous poly(vinyl chloride)
List two important characteristics for polymers that are to be used in fiber applications.
Briefly explain how each of the following influ\(\Theta\) ences the tensile or yield strength of a semicrystalline polymer and why: (a) molecular weight (b) degree of crystallinity (c) deformation by drawing (d) annealing of an undeformed material
Briefly explain the difference in molecular chemistry between silicone polymers and other polymeric materials.
For each of the following pairs of polymers, do ( the following: (1) State whether it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. (a) Linear and isotactic poly(vinyl chloride) with a weight-average molecular weight of \(100,000 \mathrm{~g} /\) mol; branched and atactic poly(vinyl chloride) having a weight-average molecular weight of \(75,000 \mathrm{~g} / \mathrm{mol}\) (b) Graft acrylonitrile-butadiene copolymer with \(10 \%\) of possible sites crosslinked; alternating acrylonitrile-butadiene copolymer with \(5 \%\) of possible sites crosslinked (c) Network polyester; lightly branched polytetrafluoroethylene
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