Chapter 15: Problem 5
In your own words, briefly describe the phenomenon of viscoelasticity.
Chapter 15: Problem 5
In your own words, briefly describe the phenomenon of viscoelasticity.
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Get started for freeWhich of the following polymers would be suit( able for the fabrication of cups to contain hot coffee: polyethylene, polypropylene, poly(vinyl chloride), PET polyester, and polycarbonate. Why?
For each of the following pairs of polymers, plot and label schematic specific volume-versustemperature curves on the same graph [i.e., make separate plots for parts (a) to \((\mathrm{c})]\) (a) Linear polyethylene with a weight-average molecular weight of \(75,000 \mathrm{~g} / \mathrm{mol}\); branched polyethylene with a weight-average molecular weight of \(50,000 \mathrm{~g} / \mathrm{mol}\) (b) Spherulitic poly(vinyl chloride) of \(50 \%\) crystallinity and having a degree of polymerization of 5000 ; spherulitic polypropylene of \(50 \%\) crystallinity and degree of polymerization of 10,000 (c) Totally amorphous polystyrene having a degree of polymerization of 7000 ; totally amorphous polypropylene having a degree of polymerization of 7000
(a) Contrast the manner in which stress relaxation and viscoelastic creep tests are conducted. (b) For each of these tests, cite the experimental parameter of interest and how it is determined.
Cite the primary differences between addition and condensation polymerization techniques.
For the vulcanization of polyisoprene, com\(+\) pute the weight percent of sulfur that must be added to ensure that \(10 \%\) of possible sites will be crosslinked; assume that, on the average, \(3.5\) sulfur atoms are associated with each crosslink.
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