Chapter 17: Problem 22
For each form of corrosion other than uniform, do the following: (a) Describe why, where, and the conditions under which the corrosion occurs. (b) Cite three measures that may be taken to nrevent or control it
Chapter 17: Problem 22
For each form of corrosion other than uniform, do the following: (a) Describe why, where, and the conditions under which the corrosion occurs. (b) Cite three measures that may be taken to nrevent or control it
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Get started for free(a) What are inhibitors? (b) What possible mechanisms account for their effectiveness?
(a) Demonstrate that the CPR is related to the corrosion current density \(i\left(\mathrm{~A} / \mathrm{cm}^{2}\right)\) through the expression $$ \mathrm{CPR}=\frac{K A i}{n \rho} $$ where \(K\) is a constant, \(A\) is the atomic weight of the metal experiencing corrosion, \(n\) is the number of electrons associated with the ionization of each metal atom, and \(\rho\) is the density of the metal. (b) Calculate the value of the constant \(K\) for the CPR in mpy and \(i\) in \(\mu \mathrm{A} / \mathrm{cm}^{2}\left(10^{-6} \mathrm{~A} / \mathrm{cm}^{2}\right)\).
Briefly explain why cold-worked metals are more susceptible to corrosion than non-coldworked metals.
(a) Write the possible oxidation and reduction half-reactions that occur when magnesium is immersed in each of the following solutions: (i) HCl, (ii) an HCl solution containing dissolved oxygen, and (iii) an HCl solution containing dissolved oxygen and \(\mathrm{Fe}^{2+}\) ions. (b) In which of these solutions would you expect the magnesium to oxidize most rapidly? Why?
A thick steel sheet of area 100 in. \(^{2}\) is exposed to air near the ocean. After a one-year period it was found to experience a weight loss of \(485 \mathrm{~g}\) due to corrosion. To what rate of corrosion, in both mpy and \(\mathrm{mm} / \mathrm{yr}\), does this correspond?
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