Chapter 2: Problem 10
Potassium iodide (KI) exhibits predominantly ionic bonding. The \(\mathrm{K}^{+}\)and \(\mathrm{I}^{-}\)ions have electron structures that are identical to which two inert gases?
Short Answer
Expert verified
The electron structures of K⁺ and I⁻ ions resemble the electron structures of Argon (Ar) and Xenon (Xe), respectively.
Step by step solution
01
Determine the electron configuration of potassium and iodine
Before calculating the ion's electron configurations, we need the electron configurations for potassium (K) and iodine (I). Potassium has 19 electrons \((\mathrm{Z} = 19)\) and it is located in Group 1 and Period 4, while iodine has 53 electrons \((\mathrm{Z} = 53)\) and it is located in Group 17 and Period 5. Their electron configurations are as follows:
Potassium (K): \(1\mathrm{s}^2 2\mathrm{s}^2 2\mathrm{p}^6 3\mathrm{s}^2 3\mathrm{p}^6 4\mathrm{s}^1\)
Iodine (I): \(1\mathrm{s}^2 2\mathrm{s}^2 2\mathrm{p}^6 3\mathrm{s}^2 3\mathrm{p}^6 4\mathrm{s}^2 3\mathrm{d}^{10} 4\mathrm{p}^6 5\mathrm{s}^2 4\mathrm{d}^{10} 5\mathrm{p}^5\)
02
Calculate the electron configurations of \(\mathrm{K}^{+}\) and \(\mathrm{I}^{-}\) ions
When potassium forms the \(\mathrm{K}^{+}\) ion, it loses one electron from its outermost shell. The electron configuration of \(\mathrm{K}^{+}\) ion will be:
\(\mathrm{K}^{+}\): \(1\mathrm{s}^2 2\mathrm{s}^2 2\mathrm{p}^6 3\mathrm{s}^2 3\mathrm{p}^6\)
When iodine forms the \(\mathrm{I}^{-}\) ion, it gains one electron in its outermost shell. The electron configuration of \(\mathrm{I}^{-}\) ion will be:
\(\mathrm{I}^{-}\): \(1\mathrm{s}^2 2\mathrm{s}^2 2\mathrm{p}^6 3\mathrm{s}^2 3\mathrm{p}^6 4\mathrm{s}^2 3\mathrm{d}^{10} 4\mathrm{p}^6 5\mathrm{s}^2 4\mathrm{d}^{10} 5\mathrm{p}^6\)
03
Compare the electron configurations of ions with inert gases
Now, let's compare the electron configurations of the \(\mathrm{K}^{+}\) and \(\mathrm{I}^{-}\) ions with the electron configurations of inert gases. Inert gases have full outer electron shells, giving them a stable configuration. There are six inert gases: helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), and radon (Rn). Their electron configurations are:
Helium (He): \(1\mathrm{s}^2\)
Neon (Ne): \(1\mathrm{s}^2 2\mathrm{s}^2 2\mathrm{p}^6\)
Argon (Ar): \(1\mathrm{s}^2 2\mathrm{s}^2 2\mathrm{p}^6 3\mathrm{s}^2 3\mathrm{p}^6\)
Krypton (Kr): \(1\mathrm{s}^2 2\mathrm{s}^2 2\mathrm{p}^6 3\mathrm{s}^2 3\mathrm{p}^6 4\mathrm{s}^2 3\mathrm{d}^{10} 4\mathrm{p}^6\)
Xenon (Xe): \(1\mathrm{s}^2 2\mathrm{s}^2 2\mathrm{p}^6 3\mathrm{s}^2 3\mathrm{p}^6 4\mathrm{s}^2 3\mathrm{d}^{10} 4\mathrm{p}^6 5\mathrm{s}^2 4\mathrm{d}^{10} 5\mathrm{p}^6\)
Radon (Rn): \(1\mathrm{s}^2 2\mathrm{s}^2 2\mathrm{p}^6 3\mathrm{s}^2 3\mathrm{p}^6 4\mathrm{s}^2 3\mathrm{d}^{10} 4\mathrm{p}^6 5\mathrm{s}^2 4\mathrm{d}^{10} 5\mathrm{p}^6 6\mathrm{s}^2 4\mathrm{f}^{14} 5\mathrm{d}^{10} 6\mathrm{p}^6\)
Comparing the electron configurations, we find that:
- \(\mathrm{K}^{+}\) ion has the same electron configuration as Argon (Ar)
- \(\mathrm{I}^{-}\) ion has the same electron configuration as Xenon (Xe)
04
Conclusion
The electron structures of \(\mathrm{K}^{+}\) and \(\mathrm{I}^{-}\) ions are identical to the electron structures of the inert gases Argon (Ar) and Xenon (Xe), respectively.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Electron Configuration
Understanding the electron configuration of an element is crucial for grasping many aspects of chemistry, particularly ionic bonding. An electron configuration describes the distribution of electrons in an atom or ion among the different levels and subshells available based on their energy. For example, the electron configuration of potassium (K) is written as 1s2 2s2 2p6 3s2 3p6 4s1, where the numbers represent the energy level (or shell), the letters (s, p, d, f) indicate the subshell type, and the superscripted numbers denote the number of electrons in each subshell.
When potassium loses an electron to become a K+ ion, it sheds the electron from its highest energy level, which is the fourth level 's' subshell. Thus, it attains a noble gas electron configuration just like argon (Ar), known for its full outer shell and stability. This process of ion formation through loss or gain of electrons is at the heart of ionic bonding. Maintaining an awareness of these configurations enables us to predict and comprehend the ions' characteristics and the bonds they form.
When potassium loses an electron to become a K+ ion, it sheds the electron from its highest energy level, which is the fourth level 's' subshell. Thus, it attains a noble gas electron configuration just like argon (Ar), known for its full outer shell and stability. This process of ion formation through loss or gain of electrons is at the heart of ionic bonding. Maintaining an awareness of these configurations enables us to predict and comprehend the ions' characteristics and the bonds they form.
Inert Gases
Inert gases, also known as noble gases, are a unique group in the periodic table occupying Group 18. They include helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), and radon (Rn).
What sets these gases apart is their complete outer electron shells, which render them extremely stable and largely nonreactive. This stability is due to the full valence shell that follows the octet rule, which states that atoms tend to gain, lose, or share electrons to have eight in their outer shell, except for helium, which is stable with two. When elements form ions, they often do so to emulate the electron configuration of inert gases, thus achieving stability. This is observed in the example of potassium iodide (KI), where upon formation of ions, potassium attains the electron configuration of argon, and iodine that of xenon, highlighting the significance of inert gases as a benchmark for chemical stability.
What sets these gases apart is their complete outer electron shells, which render them extremely stable and largely nonreactive. This stability is due to the full valence shell that follows the octet rule, which states that atoms tend to gain, lose, or share electrons to have eight in their outer shell, except for helium, which is stable with two. When elements form ions, they often do so to emulate the electron configuration of inert gases, thus achieving stability. This is observed in the example of potassium iodide (KI), where upon formation of ions, potassium attains the electron configuration of argon, and iodine that of xenon, highlighting the significance of inert gases as a benchmark for chemical stability.
Potassium Iodide
Potassium iodide (KI) serves as an exemplary case of ionic bonding, a type of chemical linkage between two atoms with opposite charges. In KI, potassium (K) and iodine (I), both with distinct electron configurations, create ions through electron transfer. K loses an electron and becomes K+, with a positive charge, while I gains an electron, resulting in I- with a negative charge.
These ions pair due to their opposing charges and form a firm ionic bond, distinctive for the resultant compound's high melting and boiling points, as well as its ability to conduct electricity when dissolved in water. Ionic compounds like potassium iodide are essential in various fields, including medicine and nutrition. By comprehending ionic bonding through examples like KI, students gain a deeper awareness of how atoms combine to form the vast array of substances we encounter in daily life.
These ions pair due to their opposing charges and form a firm ionic bond, distinctive for the resultant compound's high melting and boiling points, as well as its ability to conduct electricity when dissolved in water. Ionic compounds like potassium iodide are essential in various fields, including medicine and nutrition. By comprehending ionic bonding through examples like KI, students gain a deeper awareness of how atoms combine to form the vast array of substances we encounter in daily life.