Chapter 2: Problem 27
What type(s) of bonding would be expected for each of the following materials: solid xenon, calcium fluoride \(\left(\mathrm{CaF}_{2}\right)\), bronze, cadmium telluride (CdTe), rubber, and tungsten?
Chapter 2: Problem 27
What type(s) of bonding would be expected for each of the following materials: solid xenon, calcium fluoride \(\left(\mathrm{CaF}_{2}\right)\), bronze, cadmium telluride (CdTe), rubber, and tungsten?
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Get started for freeThe atomic radii of \(\mathrm{Mg}^{2+}\) and \(\mathrm{F}^{-}\)ions are \(0.072\) and \(0.133 \mathrm{~nm}\), respectively. (a) Calculate the force of attraction between these two ions at their equilibrium interionic separation (i.e., when the ions just touch one another). (b) What is the force of repulsion at this same separation distance?
For an \(\mathrm{Na}^{+}-\mathrm{Cl}^{-}\)ion pair, attractive and repulsive energies \(E_{A}\) and \(E_{R}\), respectively, depend on the distance between the ions \(r\), according to $$ \begin{aligned} &E_{A}=-\frac{1.436}{r} \\ &E_{R}=\frac{7.32 \times 10^{-6}}{r^{8}} \end{aligned} $$ For these expressions, energies are expressed in electron volts per \(\mathrm{Na}^{+}-\mathrm{Cl}^{-}\)pair, and \(r\) is the distance in nanometers. The net energy \(E_{N}\) is just the sum of the preceding two expressions. (a) Superimpose on a single plot \(E_{N}, E_{R}\), and \(E_{A}\) versus \(r\) up to \(1.0 \mathrm{~nm}\). (b) On the basis of this plot, determine (i) the equilibrium spacing \(r_{0}\) between the \(\mathrm{Na}^{+}\)and \(\mathrm{Cl}^{-}\) ions, and (ii) the magnitude of the bonding energy \(E_{0}\) between the two ions. (c) Mathematically determine the \(r_{0}\) and \(E_{0}\) values using the solutions to Problem 2.18, and compare these with the graphical results from part (b).
With regard to electron configuration, what do all the elements in Group IIA of the periodic table have in common?
To what group in the periodic table would an element with atomic number 112 belong?
Compute \%IC of the interatomic bond for each of the following compounds: \(\mathrm{MgO}, \mathrm{GaP}, \mathrm{CsF}\), \(\mathrm{CdS}\), and \(\mathrm{FeO}\).
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