Chapter 2: Problem 9
Give the electron configurations for the following ions: \(\mathrm{P}^{5+}, \mathrm{P}^{3-}, \mathrm{Sn}^{4+}, \mathrm{Se}^{2-}, \mathrm{I}^{-}\), and \(\mathrm{Ni}^{2+}\)
Chapter 2: Problem 9
Give the electron configurations for the following ions: \(\mathrm{P}^{5+}, \mathrm{P}^{3-}, \mathrm{Sn}^{4+}, \mathrm{Se}^{2-}, \mathrm{I}^{-}\), and \(\mathrm{Ni}^{2+}\)
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Get started for freeWith regard to electron configuration, what do all the elements in Group IIA of the periodic table have in common?
Explain why hydrogen fluoride (HF) has a higher boiling temperature than hydrogen chloride \((\mathrm{HCl})\left(19.4^{\circ} \mathrm{C}\right.\) vs. \(\left.-85^{\circ} \mathrm{C}\right)\), even though HF has a lower molecular weight.
The net potential energy between two adjacent ions, \(E_{N}\), may be represented by the sum of Equations \(2.9\) and \(2.11\); that is, $$ E_{N}=-\frac{A}{r}+\frac{B}{r^{n}} $$ Calculate the bonding energy \(E_{0}\) in terms of the parameters \(A, B\), and \(n\) using the following procedure: 1\. Differentiate \(E_{N}\) with respect to \(r\), and then set the resulting expression equal to zero, because the curve of \(E_{N}\) versus \(r\) is a minimum at \(E_{0}\). 2\. Solve for \(r\) in terms of \(A, B\), and \(n\), which yields \(r_{0}\), the equilibrium interionic spacing. 3\. Determine the expression for \(E_{0}\) by substituting \(r_{0}\) into Equation 2.17.
For an \(\mathrm{Na}^{+}-\mathrm{Cl}^{-}\)ion pair, attractive and repulsive energies \(E_{A}\) and \(E_{R}\), respectively, depend on the distance between the ions \(r\), according to $$ \begin{aligned} &E_{A}=-\frac{1.436}{r} \\ &E_{R}=\frac{7.32 \times 10^{-6}}{r^{8}} \end{aligned} $$ For these expressions, energies are expressed in electron volts per \(\mathrm{Na}^{+}-\mathrm{Cl}^{-}\)pair, and \(r\) is the distance in nanometers. The net energy \(E_{N}\) is just the sum of the preceding two expressions. (a) Superimpose on a single plot \(E_{N}, E_{R}\), and \(E_{A}\) versus \(r\) up to \(1.0 \mathrm{~nm}\). (b) On the basis of this plot, determine (i) the equilibrium spacing \(r_{0}\) between the \(\mathrm{Na}^{+}\)and \(\mathrm{Cl}^{-}\) ions, and (ii) the magnitude of the bonding energy \(E_{0}\) between the two ions. (c) Mathematically determine the \(r_{0}\) and \(E_{0}\) values using the solutions to Problem 2.18, and compare these with the graphical results from part (b).
Potassium iodide (KI) exhibits predominantly ionic bonding. The \(\mathrm{K}^{+}\)and \(\mathrm{I}^{-}\)ions have electron structures that are identical to which two inert gases?
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