Cite the phases that are present and the phase compositions for the following alloys: (a) \(15 \mathrm{wt} \% \mathrm{Sn}-85 \mathrm{wt} \% \mathrm{~Pb}\) at \(100^{\circ} \mathrm{C}\left(212^{\circ} \mathrm{F}\right)\) (b) \(25 \mathrm{wt} \% \mathrm{~Pb}-75 \mathrm{wt} \% \mathrm{Mg}\) at \(425^{\circ} \mathrm{C}\left(800^{\circ} \mathrm{F}\right)\) (c) \(85 \mathrm{wt} \% \mathrm{Ag}-15 \mathrm{wt} \% \mathrm{Cu}\) at \(800^{\circ} \mathrm{C}\left(1470^{\circ} \mathrm{F}\right)\) (d) \(55 \mathrm{wt} \% \mathrm{Zn}-45 \mathrm{wt} \% \mathrm{Cu}\) at \(600^{\circ} \mathrm{C}\left(1110^{\circ} \mathrm{F}\right)\) (e) \(1.25 \mathrm{~kg} \mathrm{Sn}\) and \(14 \mathrm{~kg} \mathrm{~Pb}\) at \(200^{\circ} \mathrm{C}\left(390^{\circ} \mathrm{F}\right)\) (f) \(7.6 \mathrm{lb}_{\mathrm{m}} \mathrm{Cu}\) and \(144.4 \mathrm{lb}_{\mathrm{m}} \mathrm{Zn}\) at \(600^{\circ} \mathrm{C}\left(1110^{\circ} \mathrm{F}\right)\) (g) \(21.7 \mathrm{~mol} \mathrm{Mg}\) and \(35.4 \mathrm{~mol} \mathrm{~Pb}\) at \(350^{\circ} \mathrm{C}\left(660^{\circ} \mathrm{F}\right)\) (h) \(4.2 \mathrm{~mol} \mathrm{Cu}\) and \(1.1 \mathrm{~mol} \mathrm{Ag}\) at \(900^{\circ} \mathrm{C}\left(1650^{\circ} \mathrm{F}\right)\)

Short Answer

Expert verified
Answer: Single-phase: α-phase; \(89 \text{ wt% Pb}\) and \(11 \text{ wt% Sn}\).

Step by step solution

01

Locate the appropriate phase diagram

Using binary phase diagrams, find the diagrams for each of the systems mentioned in the exercise. To do that, you can consult relevant materials science textbooks or reliable online resources, and it is advised to refer to the problem description for the corresponding percentage of components and temperature so that the phase composition can be correctly determined.
02

Read the phase diagram

First, locate the point corresponding to the given composition and temperature for each system on the phase diagram. Then, identify the equilibrium phases as well as their compositions for that specific point. Note that the composition axis refers to the weight or molar percentage, while the temperature axis refers to the temperature in Celsius or Fahrenheit.
03

Present the results

After identifying the equilibrium phases and composition of each alloy, present the results in the requested format. The solution to all alloys in the given exercise is shown below: (a) \(15 \mathrm{wt} \% \mathrm{Sn}-85 \mathrm{wt} \% \mathrm{~Pb} \text{ at }100^{\circ} \mathrm{C}(212^{\circ} \mathrm{F})\text{ : }\) Single-phase: α-phase; \(89 \text{ wt% Pb}\) and \(11 \text{ wt% Sn}\). (b) \(25 \mathrm{wt} \% \mathrm{~Pb}-75 \mathrm{wt} \% \mathrm{Mg} \text{ at }425^{\circ} C(800^{\circ} F) \text{ : }\) Single-phase: β-phase; \(73 \text{ wt% Mg}\) and \(27\text{ wt% Pb}\). (c) \(85 \mathrm{wt} \% \mathrm{Ag}-15 \mathrm{wt} \% \mathrm{Cu} \text{ at }800^{\circ} \mathrm{C}(1470^{\circ} \mathrm{F})\text{ : }\) Single-phase: γ-phase; \(80\text{ wt% Ag}\) and \(20 \text{ wt% Cu}\). (d) \(55 \mathrm{wt} \% \mathrm{Zn}-45 \mathrm{wt} \% \mathrm{Cu} \text{ at }600^{\circ} \mathrm{C}(1110^{\circ} \mathrm{F})\text{ : }\) Two phases: α-phase (\(78\text{ wt% Cu}\) and \(22\text{ wt% Zn}\)) and β-phase (\(98\text{ wt% Zn}\) and \(2\text{ wt% Cu}\)). (e) \(1.25 \mathrm{~kg} \mathrm{Sn}\) and \(14 \mathrm{~kg} \mathrm{~Pb} \text{ at }200^{\circ} \mathrm{C}(390^{\circ} \mathrm{F})\text{ : }\) Single-phase: α-phase; \(89\text{ wt% Pb}\) and \(11\text{ wt% Sn}\). (f) \(7.6 \mathrm{lb}_{\mathrm{m}} \mathrm{Cu}\) and \(144.4 \mathrm{lb}_{\mathrm{m}} \mathrm{Zn} \text{ at }600^{\circ} C(1110^{\circ} F)\text{ : }\) Two phases: α-phase (\(78\text{ wt% Cu}\) and \(22\text{ wt% Zn}\)) and β-phase (\(98\text{ wt% Zn}\) and \(2\text{ wt% Cu}\)). (g) \(21.7 \mathrm{~mol} \mathrm{Mg}\) and \(35.4 \mathrm{~mol} \mathrm{~Pb} \text{ at }350^{\circ} C(660^{\circ} F)\text{ : }\) Single-phase: β-phase; \(73 \text{ wt% Mg}\) and \(27\text{ wt% Pb}\). (h) \(4.2 \mathrm{~mol} \mathrm{Cu}\) and \(1.1 \mathrm{~mol} \mathrm{Ag} \text{ at }900^{\circ} C(1650^{\circ} F)\text{ : }\) Single-phase: γ-phase; \(80\text{ wt% Ag}\) and \(20 \text{ wt% Cu}\).

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