What is the principal difference between congruent and incongruent phase transformations?

Short Answer

Expert verified
The principal difference between congruent and incongruent phase transformations lies in the change (or lack thereof) in the composition of the substance during the transformation. In a congruent phase transformation, the composition remains the same throughout the transformation process, while in an incongruent phase transformation, the composition changes as the transformation takes place.

Step by step solution

01

Define Congruent Phase Transformation

In a congruent phase transformation, there is no change in the composition of the substance when it transforms from one phase to another. In other words, the chemical composition of the phases involved in the transformation remains the same. Examples of congruent phase transformations include melting and freezing of pure substances like water.
02

Define Incongruent Phase Transformation

In an incongruent phase transformation, there is a change in the composition of the substance as it transforms from one phase to another. As the transformation occurs, the elements or compounds involved in the transition redistribute themselves between the phases, resulting in different chemical compositions. Examples of incongruent phase transformations are the decomposition of limestone (CaCO3) into calcium oxide (CaO) and carbon dioxide (CO2), and the eutectoid transformation in iron-carbon alloys.
03

Principal Difference Between Congruent and Incongruent Phase Transformations

The principal difference between congruent and incongruent phase transformations lies in the change (or lack thereof) in the composition of the substance during the transformation. In a congruent phase transformation, the composition remains the same throughout the transformation process, while in an incongruent phase transformation, the composition changes as the transformation takes place.

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