By expanding an arbitraryU(x) in a power series about a local minimum assumed to be atx=a , prove that the effective spring constant is given by equation(10-3) .

Short Answer

Expert verified

The effective spring constant is given by the expansion k=d2Uxdx2a.

Step by step solution

01

Given data

a power series expansion of Uxabout local minimum at x=ais given by the expansion k=d2Uxdx2a

02

Concept of power series expansion

the expansion about x=ais given by,

f(a)+f'(a)1!(x-a)+f'(a)2!(x-a)2+....

03

Determine the potential energy between two protons

We need to prove that a power series expansion of Uxabout local minimum at x=ais given by the expansion

k=d2Uxdx2a

Applying 1on Uxabout x=a, we get

Ux-a=Ua+U'a1!x-a+U'a2!x-a2+.....

The potential energy of diatomic molecule for small oscillation with an equilibrium separation and spring constant ' k ' is given by

Ux-aU0+12kx-a2

Comparing the respective coefficients of (2) and (3), we get

U0=UaU'a2!x-a2=12kx-a2k=U''ak=d2Uxdx2a

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