Show thatΔp=0p^ψ(x)=p¯ψ(x) that is, verify that unless the wave function is an Eigen function of the momentum operator, there will be a nonzero uncertainty in the momentumstarts with showing that the quantity

allspaceψ(x)(p^p¯)2ψ(x)dx

Is (Δp)2. Then using the differential operator form ofp^and integration by parts, show that it is also,

allspace{(p^p¯)ψ(x)}{(p^p¯)ψ(x)}dx

Together these show that ifΔpis. 0. then the preceding quantity must be 0. However, the Integral of the complex square of a function(the quantity in the brackets) can only be 0 if the function is identically 0, so the assertion is proved.

Short Answer

Expert verified

The Δp=0is implies that p^ψ(x)=p¯ψ(x)is proved.

Step by step solution

01

Identification of given data

The given data can be listed below,

The difference in momentum isΔp=0,

02

Concept/Significance of the momentum operator

If the translation operator is unitary and the momentum operator is the infinitesimal generator of translations, then the momentum operator is Hermitian.

03

Determination of the wave function is an Eigen function of the momentum operator, there will be a nonzero uncertainty

TheΔp is given by,

I=allspaceψ(x)(p^p¯)2ψ(x)dx

Solve the above equation.

I=allspaceψ(x)p^2ψ(x)dx2p¯allspaceψ(x)p^ψ(x)dx+p¯2allspaceψ(x)ψ(x)dx

The value of the third integral is 1.

The solution for the integration is given by,

(Δp)2=allspaceψ(x)(ix)(ixp¯)ψ(x)dxallspaceψ(x)p¯(ixp¯)ψ(x)dx=iψ(x)(ixp¯)ψ(x)allspace(iψ(x)x)(ixp¯)ψ(x)dxallspaceψ(x)p¯(ixp¯)ψ(x)dx=0allspace(iψ(x)x)(ixp¯)ψ(x)dxallspaceψ(x)p¯(ixp¯)ψ(x)dx

Rearrange the equation for(Δp)2 noting thatp is real and that the complex conjugate of the sum of complex conjugates is itself a complex conjugate

(Δp)2=allspace((ixp¯)ψ(x))((ixp¯)ψ(x))dx

From, the above equation it is clear that

p^ψ(x)=p¯ψ(x)

Thus, the Δp=0is implies that p^ψ(x)=p¯ψ(x)is proved.

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Most popular questions from this chapter

To determine the two bound state energies for the well.

An electron in the n=4 state of a 5 nm wide infinite well makes a transition to the ground state, giving off energy in the form of photon. What is the photon’s wavelength?

Summarize the similarities are differences between the three simple bound cases considered in this chapter.

It is possible to take the finite well wave functions further than (21) without approximation, eliminating all but one normalization constant C . First, use the continuity/smoothness conditions to eliminate A, B , andG in favor of Cin (21). Then make the change of variables z=x-L/2 and use the trigonometric relations

sin(a+b)=sinacosb+cosasinband

cos(a+b)=cosacosb-sinasinbon the

functions in region I, -L/2<z<L/2. The change of variables shifts the problem so that it is symmetric about z=0, which requires that the probability density be symmetric and thus that ψ(z)be either an odd or even function of z. By comparing the region II and region III functions, argue that this in turn demands that (α/k)sinkL+coskL must be either +1 (even) or -1 (odd). Next, show that these conditions can be expressed, respectively, as αk=tankL2 and αk=-cotkL2. Finally, plug these separately back into the region I solutions and show that

ψ(z)=C×{eα(z+L/2)          z<L/2coskzcoskL2          -L/2<z<L/2e-α(z-L/2)          z>L/2


or

ψ(z)=C×{eα(z+L/2)          z<L/2-sinkzsinkL2          -L/2<z<L/2e-α(z-L/2)          z>L/2

Note that Cis now a standard multiplicative normalization constant. Setting the integral of |ψ(z)|2 over all space to 1 would give it in terms of kand α , but because we can’t solve (22) exactly for k(or E), neither can we obtain an exact value for C.

Obtain expression (5-23) from equation (5-22). Using cosθ=cos2(12θ)sin2(12θ)andsinθ=2sin(12θ)cos(12θ), first convert the argument of the cotangent fromkLto12kL. Next, put the resulting equation in quadratic form, and then factor. Note thatαis positive by definition.

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