Chapter 5: Q82CE (page 193)
Calculate the expectation value of the position of the particle.
Short Answer
The expectation value of the position of the particle is .
Chapter 5: Q82CE (page 193)
Calculate the expectation value of the position of the particle.
The expectation value of the position of the particle is .
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Get started for freeConsider a particle bound in a infinite well, where the potential inside is not constant but a linearly varying function. Suppose the particle is in a fairly high energy state, so that its wave function stretches across the entire well; that is isn’t caught in the “low spot”. Decide how ,if at all, its wavelength should vary. Then sketch a plausible wave function.
For a total energy of 0, the potential energy is given in Exercise 96. (a) Given these, to what region of the x-axis would a classical particle be restricted? Is the quantum-mechanical particle similarly restricted? (b) Write an expression for the probability that the (quantum-mechanical) particle would be found in the classically forbidden region, leaving it in the form of an integral. (The integral cannot be evaluated in closed form.)
There are mathematical solutions to the Schrödinger equation for the finite well for any energy, and in fact. They can be made smooth everywhere. Guided by A Closer Look: Solving the Finite Well. Show this as follows:
(a) Don't throw out any mathematical solutions. That is in region Il , assume that , and in region III , assume that. Write the smoothness conditions.
(b) In Section 5.6. the smoothness conditions were combined to eliminate in favor of . In the remaining equation. canceled. leaving an equation involving only and , solvable for only certain values of . Why can't this be done here?
(c) Our solution is smooth. What is still wrong with it physically?
(d) Show that
localid="1660137122940"
and that setting these offending coefficients to 0 reproduces quantization condition (5-22).
Air is mostly N2, diatomic nitrogen, with an effective spring constant of 2.3 x 103N/m, and an effective oscillating mass of half the atomic mass. For roughly what temperatures should vibration contribute to its heat capacity?
equation (5-33). The twosolutionsare added in equal amounts. Show that if we instead added a different percentage of the two solutions. It would not change the important conclusion related to the oscillation frequency of the charge density.
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