Chapter 5: Q84CE (page 193)
Determine the expectation value of the momentum of the particle. Explain.
Short Answer
The expected value of momentum is .
Chapter 5: Q84CE (page 193)
Determine the expectation value of the momentum of the particle. Explain.
The expected value of momentum is .
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Get started for freeAir is mostly N2, diatomic nitrogen, with an effective spring constant of 2.3 x 103N/m, and an effective oscillating mass of half the atomic mass. For roughly what temperatures should vibration contribute to its heat capacity?
Figure 5.15 shows that the allowed wave functions for a finite well whose depth was chosen to be.
(a) Insert this value in equation (5-23), then using a calculator or computer, solve for the allowed value of , of which there are four.
(b) Usingfind corresponding values of E. Do they appear to agree with figure 5.15?
(c) Show that the chosenimplies that .
(d) Definingandto be 1 for convenience, plug your and values into the wave function given in exercise 46, then plot the results. ( Note: Your first and third values should correspond to even function of z, thus using the form with, while the second and forth correspond to odd functions. Do the plots also agree with Figure 5.15?
To show that the potential energy of finite well is
Show that the uncertainty in a particle’s position in an infinite well in the general case of arbitrary is given by
Discuss the dependence. In what circumstance does it agree with the classical uncertainty of discussed in Exercise 55?
There are mathematical solutions to the Schrödinger equation for the finite well for any energy, and in fact. They can be made smooth everywhere. Guided by A Closer Look: Solving the Finite Well. Show this as follows:
(a) Don't throw out any mathematical solutions. That is in region Il , assume that , and in region III , assume that. Write the smoothness conditions.
(b) In Section 5.6. the smoothness conditions were combined to eliminate in favor of . In the remaining equation. canceled. leaving an equation involving only and , solvable for only certain values of . Why can't this be done here?
(c) Our solution is smooth. What is still wrong with it physically?
(d) Show that
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and that setting these offending coefficients to 0 reproduces quantization condition (5-22).
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