Chapter 7: Q36E (page 281)
Prove that if the functionis to meet itself smoothly whenchanges by , must be an integer.
Short Answer
For the function to have a period of , must be an integer.
Chapter 7: Q36E (page 281)
Prove that if the functionis to meet itself smoothly whenchanges by , must be an integer.
For the function to have a period of , must be an integer.
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Get started for freeQuestion: A particle is trapped in a spherical infinite well. The potential energy is 0for r < a and infinite for r > a . Which, if any, quantization conditions would you expect it to share with hydrogen, and why?
For a hydrogen atom in the ground state. determine (a) the most probable location at which to find the electron and (b) the most probable radius at which to find the electron, (c) Comment on the relationship between your answers in parts (a) and (b).
At heart, momentum conservation is related to the universe being "translationally invariant," meaning that it is the same if you shift your coordinates to the right or left. Angular momentum relates to rotational invariance. Use these ideas to explain at least some of the differences between the physical properties quantized in the cubic three-dimensional box versus the hydrogen atom.
Question: Consider an electron in the ground state of a hydrogen atom. (a) Calculate the expectation value of its potential energy. (b) What is the expectation value of its kinetic energy? (Hint: What is the expectation value of the total energy?)
Question: The kinetic energy of hydrogen atom wave functions for which lis its minimum value of 0 is all radial. This is the case for the 1s and 2s states. The 2 p state has some rotational kinetic energy and some radial. Show that for very large n, the states of largest allowed lhave essentially no radial kinetic energy. Exercise 55 notes that the expectation value of the kinetic energy (including both rotational and radial) equals the magnitude of the total energy. Compare this magnitude with the rotational energy alone,
,assuming that n is large. That lis as large as it can be, and that.
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