Chapter 7: Q42E (page 281)
In Appendix G. the operator for the square of the angular momentum is shown to be
Use this to rewrite equation (7-19) as
Chapter 7: Q42E (page 281)
In Appendix G. the operator for the square of the angular momentum is shown to be
Use this to rewrite equation (7-19) as
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Get started for freeA simplified approach to the question of how lis related to angular momentum – due to P. W. Milonni and Richard Feynman – can be stated as follows: If can take on only those values , where , then its square is allowed only values, and the average of localid="1659178449093" should be the sum of its allowed values divided by the number of values, , because there really is no preferred direction in space, the averages of should be the same, and sum of all three should give the average of role="math" localid="1659178641655" . Given the sumrole="math" localid="1659178770040" , show that these arguments, the average of should be .
Exercise 81 obtained formulas for hydrogen like atoms in which the nucleus is not assumed infinite, as in the chapter, but is of mass, while is the mass of the orbiting negative charge. (a) What percentage error is introduced in the hydrogen ground-state energy by assuming that the proton is of infinite mass? (b) Deuterium is a form of hydrogen in which a neutron joins the proton in the nucleus, making the nucleus twice as massive. Taking nuclear mass into account, by what percent do the ground-state energies of hydrogen and deuterium differ?
(a) What is the expectation value of the distance from the proton of an electron in a 3p state? (b) How does this compare with the expectation value in the 3 d state, calculated in Example 7.7? Discuss any differences.
Question: The kinetic energy of hydrogen atom wave functions for which lis its minimum value of 0 is all radial. This is the case for the 1s and 2s states. The 2 p state has some rotational kinetic energy and some radial. Show that for very large n, the states of largest allowed lhave essentially no radial kinetic energy. Exercise 55 notes that the expectation value of the kinetic energy (including both rotational and radial) equals the magnitude of the total energy. Compare this magnitude with the rotational energy alone,
,assuming that n is large. That lis as large as it can be, and that.
An electron is in anI = 3state of the hydrogen atom, what possible angles might the angular momentum vector make with the z-axis.
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