In Appendix G. the operator for the square of the angular momentum is shown to be

L^2=-h2[cscθθsinθθ+csc2θ2ϕ2]

Use this to rewrite equation (7-19) asL^2Φ=-Ch2Φ

Short Answer

Expert verified

L^2θΦ=-Ch2θΦ

Step by step solution

01

 Given data

The angular momentum operator is given as:

L^2=-h2[cscθθ(sinθθ)+csc2θ2ϕ2]

Where, h is the reduced Planck’s constant.

02

 Calculation

The separation of the variable of the above equation can be written as:

cscθθ(sinθθ)+csc2θ2ϕ2ΘΦ=CΘΦcscθθ(sinθΘΦθ)+csc2θ2ΘΦϕ2=CΘΦ1Θcscθθ(sinθΘθ)+csc2θ1Φ2Φϕ2=C

Now we can write the operator as:

L^2=-h2cscθθsinθθcsc2θ2ϕ2L^2Φ=-h2cscθθsinθθcsc2θ2ϕ2Φ=-h2Φcscθθsinθθ-h2Φcsc2θ2Φϕ2=-h2Φ1cscθθsinθΦθcsc2θ1Φ2Φϕ2L^2Φ=-Ch2Φ

03

 Conclusion

Thus, it can be written as L^2Φ=-Ch2Φ.

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Most popular questions from this chapter

A simplified approach to the question of how lis related to angular momentum – due to P. W. Milonni and Richard Feynman – can be stated as follows: If can take on only those values mlh, whereml=0,±1,±l , then its square is allowed only valuesml2h2, and the average of localid="1659178449093" l2should be the sum of its allowed values divided by the number of values,2l+1 , because there really is no preferred direction in space, the averages of Lx2andLy2should be the same, and sum of all three should give the average of role="math" localid="1659178641655" L2. Given the sumrole="math" localid="1659178770040" 1Sn2=N(N+1)(2N+1)/6, show that these arguments, the average of L2 should be l(l+1)h2.

Exercise 81 obtained formulas for hydrogen like atoms in which the nucleus is not assumed infinite, as in the chapter, but is of mass, m1while m2is the mass of the orbiting negative charge. (a) What percentage error is introduced in the hydrogen ground-state energy by assuming that the proton is of infinite mass? (b) Deuterium is a form of hydrogen in which a neutron joins the proton in the nucleus, making the nucleus twice as massive. Taking nuclear mass into account, by what percent do the ground-state energies of hydrogen and deuterium differ?

(a) What is the expectation value of the distance from the proton of an electron in a 3p state? (b) How does this compare with the expectation value in the 3 d state, calculated in Example 7.7? Discuss any differences.

Question: The kinetic energy of hydrogen atom wave functions for which lis its minimum value of 0 is all radial. This is the case for the 1s and 2s states. The 2 p state has some rotational kinetic energy and some radial. Show that for very large n, the states of largest allowed lhave essentially no radial kinetic energy. Exercise 55 notes that the expectation value of the kinetic energy (including both rotational and radial) equals the magnitude of the total energy. Compare this magnitude with the rotational energy alone,L2/2mr2
,assuming that n is large. That lis as large as it can be, and thatrn2a0.

An electron is in anI = 3state of the hydrogen atom, what possible angles might the angular momentum vector make with the z-axis.

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