The Kαline in copper is a very common one to use in X-ray crystallography. To produce it, electrons are accelerated through a potential difference and smashed into a copper target. Section 7.8 gives the energies in a hydrogen like atom asZ2(-13.6eV/n2) . Making the reasonable approximation that ann=1 electron in copper orbits the nucleus and half of its fellow n=1electron, being unaffected by the roughly spherical cloud of other electrons around it. Estimate the minimum accelerating potential needed to make a hole in copper'sKshell.

Short Answer

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The resultant answer is11kV

Step by step solution

01

Given data

The given data isKα line in copper is used in x-ray.

02

Concept of Energy

The energyEof the emitted ray is inversely proportional to the wavelengthλ:

E~1λ

03

Determine the charge

Since a copper nucleus has 29 protons, its charge will be +29.

However, when the K-shell electron is ejected it sees half of the other K-shell electron screening the nucleus.

That will thus make the effective charge that the ejected electron sees as +28.5.

That is used in equationE=Z2-13.6eVn2 for Z, along with 1 for (since it's the K-shell):

E=Z2-13.6eVn2E=(28.5)2-13.6eV(1)2E=-11046.6eV

In order for the electron to be ejected, the sum of that and the kinetic energy of the accelerated electron have to be at least zero.

0<KE+E0<qΔV-11046.6eVqΔV-11046.6eV

And since it's an electron that was accelerated, the charge q will be the elementary unit of charge q

11046.6eV<qΔV11046.6eV<(e)ΔV11046.6eV<ΔV

The electrons were able to drop out due to the definition of one VV being the energy that an electron gains by passing through a potential difference of one Volt.

So, the potential difference that the X-ray electron would have to be accelerated through is shown below.

ΔV=11,000VΔV=11,000V1kV1000VΔV=11kV

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Most popular questions from this chapter

Question: Show that the frequency at which an electron’s intrinsic magnetic dipole moment would process in a magnetic field is given by ωeBme. Calculate the frequency for a field of 1.0 T.

A beam of identical atoms in their ground state is sent through a Stem-Gerlach apparatus and splits into three lines. Identify possible sets {sT,LT}of their total spin and total orbital angular momentum? Ignore possibilities in which sT is 2 or higher.

Consider Z=19potassium. As a rough approximation assume that each of itsn=1electron s orbits 19 pro. tons and half an electron-that is, on average, half its fellown=1electron. Assume that each of itsn=2electrons orbits 19 protons, two Is electrons. and half of the seven othern=2electrons. Continue the process, assuming that electrons at eachorbit a correspondingly reduced positive charge. (At each, an electron also orbits some of the electron clouds of higher. but we ignore this in our rough approximation.)

(a) Calculate in terms ofa0the orbit radii of hydrogenlike atoms of these effective Z,

(b) The radius of potassium is often quoted at around0.22nm. In view of this, are yourn=1throughn=3radii reasonable?

(c) About how many more protons would have to be "unscreened" to then=4electron to agree with the quoted radius of potassium? Considering the shape of its orbit, should potassium'sn=4electron orbit entirely outside all the lower-electrons?

Summarize the connection between angular momentum quantization and the stem-Gerlach experiment.

Your friends ask: “Why is there an exclusion principle?” Explain in the simplest terms.

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