Chapter 9: Q30E (page 404)
Obtain equation (9- 15) from (9-14). Make use or the following sums, correct when :
Short Answer
Equation simplifies to equation
Chapter 9: Q30E (page 404)
Obtain equation (9- 15) from (9-14). Make use or the following sums, correct when :
Equation simplifies to equation
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Get started for freeConsider a room divided by imaginary lines into three equal parts. Sketch a two-axis plot of the number of ways of arranging particles versus andfor the case, Note that is not independent, being of courseYour axes should berole="math" localid="1658331658925" and, and the number of ways should be represented by density of shading. (A form for numbers of ways applicable to a three-sided room is given in Appendix I. but the question can be answered without it.)
At high temperature, the average energy of a classical one-dimensional oscillator is , and for an atom in a monatomic ideal gas. it is . Explain the difference. using the equipartition theorem.
The electrons’ contribution to the heat capacity of a metal is small and goes to as . We might try to calculate it via the total internal energy, localid="1660131882505" , but it is one of those integrals impossible to do in closed form, and localid="1660131274621" is the culprit. Still, we can explain why the heat capacity should go to zero and obtain a rough value.
(a) Starting withexpressed as in equation (34), show that the slope atis.
(b) Based on part (a), the accompanying figure is a good approximation to when is small. In a normal gas, such as air, whenis raised a little, all molecules, on average, gain a little energy, proportional to . Thus, the internal energy increases linearly with , and the heat capacity, , is roughly constant. Argue on the basis of the figure that in this fermion gas, as the temperature increases from to a small value , while some particles gain energy of roughly , not all do, and the number doing so is also roughly proportional to localid="1660131824460" . What effect does this have on the heat capacity?
(c)Viewing the total energy increase as simply = (number of particles whose energy increases) (energy change per particle) and assuming the density of states is simply a constant over the entire range of particle energies, show that the heat capacity under these lowest-temperature conditions should be proportional to . (Trying to be more precise is not really worthwhile, for the proportionality constant is subject to several corrections from effects we ignore).
Exercise 54 calculates the three oscillator distributions'values in the special case whereis. Using a very common approximation technique. show that in the more general low-temperature limit,occupation numbers become, and 1, for the distinguishable. boson. and fermion cases, respectively. Comment on these results. (Note: Although we assume that. we also still assume that levels are closely spaced-that is ,
We based the exact probabilities of equation (9-9) on the claim that the number of ways of addingN distinct nonnegative integer quantum numbers to give a total ofM is. Verify this claim (a) for the caseandfor the case.
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