Suppose we have a system of identical particles moving in just one dimension and for which the energy quantization relationship isE=bn2/3, wherebis a constant andan integer quantum number. Discuss whether the density of states should be independent ofE, an increasing function ofE, or a decreasing function ofE.

Short Answer

Expert verified

Based on our above expression for D(E), the density of states is thus an increasing function ofE . More accurately, the density of states is directly proportional to E1/2.

Step by step solution

01

Step 1:

In this problem, we are given the relationship between the energyEand the quantum staten:

E=bn2/3,

Whereb is constant. Our task is to determine whether the density of states D(E)is increasing, decreasing, or independent of E.

02

express  n in terms of E

Given the quantized energy equation above, let us first express nin terms of E:

E=bn2/3n2/3=Ebn=(Eb)3/2

03

expression for the density of states D(E)

Now that we have nin terms ofE, let us take the derivative of both sides:

d(n)=d(Eb)3/2dn=32E1/2b3/2dE=32Eb3dE

Dividing both sides by dEwe obtain the expression for the density of states D(E)associated with the energy relation above:

dndE=32Eb3dEdE=32Eb3D(E)=32Eb3

04

density is a increasing function

Based on our above expression for D(E), the density of states is thus an increasing function of E. More accurately, the density of states is directly proportional to E1/2.

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Most popular questions from this chapter

A two-sided room contains six particles, a, b, c, d, e and f, with two on the left and four on the right.

(a) Describe the macrostate.

(b) Identify the possible microstates. (Note: With only six particles, this isn't a thermodynamic system, but the general idea still applies, and the number of combinations is tractable.)

Density of states (9-39) does not depend on N, the total number of particles in the system; neither does the density of states in equation (9-27). Why not?

  1. Calculate the average speed of a gas molecule in a classical ideal gas.
  2. What is the average velocity of a gas molecule?

We claim that the famous exponential decrease of probability with energy is natural, the vastly most probable and disordered state given the constraints on total energy and number of particles. It should be a state of maximum entropy ! The proof involves mathematical techniques beyond the scope of the text, but finding support is good exercise and not difficult. Consider a system of11oscillators sharing a total energy of just50 . In the symbols of Section 9.3. N=11andM=5 .

  1. Using equation(9-9) , calculate the probabilities ofn , being0,1,2, and3 .
  2. How many particlesNn , would be expected in each level? Round each to the nearest integer. (Happily. the number is still 11. and the energy still50 .) What you have is a distribution of the energy that is as close to expectations is possible. given that numbers at each level in a real case are integers.
  3. Entropy is related to the number of microscopic ways the macro state can be obtained. and the number of ways of permuting particle labels withN0 ,N1,N2 , and N3fixed and totaling11 is11!(N0!N1!N2!N3!) . (See Appendix J for the proof.) Calculate the number of ways for your distribution.
  4. Calculate the number of ways if there were6 particles inn=0.5 inn=1 and none higher. Note that this also has the same total energy.
  5. Find at least one other distribution in which the 11 oscillators share the same energy, and calculate the number of ways.
  6. What do your finding suggests?

Show that in the limithω0kBT. Equation (9.15) becomes (9.28).

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