Chapter 1: Q48E (page 1)
Question: Show that the normalization constant given in Table 7.3 for the angular parts of the wave function is correct.
Short Answer
Answer
It has been proved that the normalization for the case is correct.
Chapter 1: Q48E (page 1)
Question: Show that the normalization constant given in Table 7.3 for the angular parts of the wave function is correct.
Answer
It has been proved that the normalization for the case is correct.
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Get started for freeVerify that equation (4-19) follows from (4-16) and (4-18).
As noted in example 10.2, the HD molecule differs from in that a deuterium atom replaces a hydrogen atom (a) What effect, if any, does the replacement have on the bond length and force constant? Explain. (b) What effect does it have on the rotational energy levels ? (c) And what effect does it have on the vibrational energy levels.?
Calculate the probability that the electron in a hydrogen atom would be found within 30 degrees of the xy-plane, irrespective of radius, for (a) I=0 ,; (b) role="math" localid="1660014331933" and (c) . (d) As angular momentum increases, what happens to the orbits whose z-components of angular momentum are the maximum allowed?
A function is nonzero only in the region of width centered at
where C is a constant.
(a) Find and plot versus the Fourier transform of this function.
(b) The function ) might represent a pulse occupying either finite distance (localid="1659781367200" position) or finite time (time). Comment on the wave number if is position and on the frequency spectrum if is time. Specifically address the dependence of the width of the spectrum on .
The state –2p the state in which has most of its probability density along the z-axis, and so it is often referred to as a state. To allow its probability density to stick out in other ways and thus facilitate various kinds of molecular bonding with other atoms, an atomic electron may assume a wave function that is an algebraic combination of multiple wave functions open to it. One such “hybrid state” is the sum (Note: Because the Schrodinger equation is a linear differential equation, a sum of solutions with the same energy is a solution with that energy. Also, normalization constants may be ignored in the following questions.)
(a) Write this wave function and its probability density in terms of r, , and , (Use the Euler formula to simplify your result.)
(b) In which of the following ways does this state differ from its parts (i.e., and ) and from the 2pz state: Energy? Radial dependence of its probability density? Angular dependence of its probability density?
(c) This state is offer is often referred to as the . Why?
(d) How might we produce a state?
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