As a Boeing 747 gains altitude, the passenger cabin is pressurized. However, the cabin is not pressurized fully to atmospheric $\left(1.01 \times 10^{5} \mathrm{Pa}\right),$ as it would be at sea level, but rather pressurized to \(7.62 \times 10^{4} \mathrm{Pa}\). Suppose a 747 takes off from sea level when the temperature in the airplane is \(25.0^{\circ} \mathrm{C}\) and the pressure is \(1.01 \times 10^{5} \mathrm{Pa} .\) (a) If the cabin temperature remains at \(25.0^{\circ} \mathrm{C},\) what is the percentage change in the number of moles of air in the cabin? (b) If instead, the number of moles of air in the cabin does not change, what would the temperature be?

Short Answer

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Also, what is the final temperature if the number of moles of air does not change? Answer: Using the provided steps, the percentage change in the number of moles of air is calculated as \(1 - \frac{P_2}{P_1} = 1 - \frac{7.62 × 10^4 \mathrm{Pa}}{1.01 × 10^5 \mathrm{Pa}} = 0.2465\) or \(24.65\%\). To calculate the final temperature if the number of moles does not change, we rearrange the combined gas law as \(\frac{P_1V_1}{T_1} = \frac{P_2V_2}{T_2}\) and solve for \(T_2\).

Step by step solution

01

(Step 1: Calculate the initial pressure and volume of the air inside the cabin)

Since we are given the pressure and temperature of the air inside the cabin, we can use the ideal gas law to calculate the initial volume (assuming an ideal gas): Here, we'll let \(P_1 = 1.01 \times 10^5 \mathrm{Pa},\ T_1 = 25.0^{\circ} \mathrm{C} = 298.15\ \mathrm{K}\).
02

(Step 2: Calculate the final volume of the air inside the cabin given the new pressure at altitude)

Now, we're given that the final pressure in the cabin at altitude is \(7.62 \times 10^4 \mathrm{Pa}\), which we'll label \(P_2\). Since the initial and final conditions of pressure and temperature are given, we can find the final volume of air in the cabin. Because the temperature remains the same, we can apply Boyle's Law, which states the following : \({P_1V_1=P_2V_2}\)
03

(Step 3: Calculate the percentage change in the number of moles of air)

By comparing the initial and final volume, we can calculate the percentage change in the number of moles of air, \((\Delta n)/n\). We can rewrite the ideal gas law as follows: \(\frac{P_1V_1}{RT_1} = n_1\) and \(\frac{P_2V_2}{RT_2} = n_2\) Since temperature remains constant, we can write the relationship between the initial and final number of moles as: \(\frac{\Delta n}{n} = 1 - \frac{n_2}{n_1} = 1 - \frac{P_2}{P_1}\). This can be used to compute the percentage change.
04

(Step 4: Calculate the final temperature if the number of moles of air does not change)

For this part, we assume that the number of moles of air does not change (\(n_1 = n_2\)). So, the ideal gas laws for initial and final states are: \(P_1V_1 = nRT_1\) and \(P_2V_2 = nRT_2\) As temperature changes, we can't apply Boyle's law here. Instead, we have to apply the combined gas law: \(\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}\) Since the number of moles is constant, in this case, we can rearrange the equation and solve for \(T_2\).

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