Chapter 1: Problem 4
As the temperature of the gas decreases, its density _____.
Short Answer
Expert verified
Answer: When the temperature of a gas decreases while keeping pressure and molar mass constant, its density increases. This happens because the relationship between temperature and density is inverse, as shown by the derived formula ρ = MP/(RT).
Step by step solution
01
Recall the ideal gas law
The ideal gas law is a fundamental relationship between the pressure, volume, temperature, and amount of an ideal gas. It is given by the equation:
PV = nRT
where P is the pressure, V is the volume, n is the number of moles of the gas, R is the ideal gas constant, and T is the temperature in Kelvin.
02
Relate density to the ideal gas law
In order to relate density to the ideal gas law, we'll need to define density. The density (ρ) of a substance is defined as the mass (m) divided by its volume (V):
ρ = m/V
We also know that the mass of a gas can be expressed as the product of the number of moles (n) and the molar mass of the gas (M):
m = nM
Substituting the mass expression into the density formula, we obtain:
ρ = nM/V
03
Combine the ideal gas law and the density formula
Now, we'll express the volume (V) from the ideal gas law and substitute it into the above density formula:
V = nRT/P
Plugging this into the density formula, we get:
ρ = nM/(nRT/P)
The n in the numerator and denominator will cancel out:
ρ = MP/(RT)
04
Analyze the relationship between temperature and density
From the derived formula, ρ = MP/(RT), we can see that density (ρ) is inversely proportional to temperature (T), as long as pressure (P) and molar mass (M) remain constant.
05
Conclusion
As the temperature of the gas decreases, its density increases. This is because the relationship between temperature and density is inverse, as shown by the derived formula ρ = MP/(RT), with constant pressure and molar mass.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Relationship Between Temperature and Density
Understanding how temperature affects the density of gases is critical in various scientific applications. This relationship reveals that when the temperature of a gas decreases, provided the pressure is constant, its density will indeed increase. This correlation is a direct result of the principles of the ideal gas law.In more detail, if we hold pressure (P) and molar mass (M) constant, and we decrease the temperature (T), then according to the formula calculated in the solutions—density (ρ) = Molar mass (M) × Pressure (P) / Ideal gas constant (R) × Temperature (T)—we observe that the variable 'T' in the denominator makes the relationship an inverse one. In simple words, as temperature goes down, the number describing the density must go up, if all else is equal. This is because the volume of the gas will diminish as the molecules lose kinetic energy and come closer together at lower temperatures, which means the same amount of mass occupies less space, thus increasing density.
Density of a Substance
The concept of density, denoted by the Greek letter rho (ρ), fundamentally measures how much mass is contained in a given volume of a substance. It is a crucial physical property that helps differentiate between materials and is particularly important when considering buoyancy, purity and material design.Density is expressed as mass (m) per volume (V), and its units are generally grams per cubic centimeter (g/cm³) or kilograms per cubic meter (kg/m³). The formula looks like this:Density (ρ) = Mass (m) / Volume (V)To explain it in an everyday context, consider two objects of the same size; one made of lead and the other of aluminum. Even though they occupy the same space, the lead object is much heavier due to its higher density. This translates into more mass per unit of volume. In gases, which are compressible, density can be significantly affected by changes in temperature and pressure.
Molar Mass
Molar mass is a property of a substance that tells us the mass, in grams, of one mole of that substance. The term 'mole' represents a constant number of particles, specifically Avogadro's number (6.022 × 10²³), of molecules or atoms. The molar mass is expressed in units of grams per mole (g/mol) and varies from substance to substance depending on the types of atoms and the number of atoms present in the molecules of the substance.For instance, the molar mass of water (H₂O) is about 18 g/mol, meaning that one mole of water weighs about 18 grams. This concept is vital for chemists when calculating how much of a chemical is needed for a reaction or when determining the mass of a given number of particles of a substance. It directly relates to the ideal gas law when we look at the density of a gas because knowing the molar mass allows you to find the mass present in any given volume, contributing to the formula for density when considering a gas.