Chapter 41: Q. 18 (page 1207)
sodium atoms are excited to the state at s. How many of these atoms remain in the state at
(a)
(b), and
(c) ?
Short Answer
(a). The atoms is .
(b). The atoms is .
(c). The atoms is.
Chapter 41: Q. 18 (page 1207)
sodium atoms are excited to the state at s. How many of these atoms remain in the state at
(a)
(b), and
(c) ?
(a). The atoms is .
(b). The atoms is .
(c). The atoms is.
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Get started for freeThe ionization energy of an atom is known to be . The emission spectrum of this atom contains only the four wavelengths and . Draw an energy-level diagram with the fewest possible energy levels that agrees with these experimental data. Label each level with an appropriate quantum number. Hint: Don’t forget about the selection rule.
Identify the element for each of these electron configurations. Then determine whether this configuration is the ground state or an excited state.
a.
b.
List the quantum numbers, excluding spin, of
(a) all possible states and
(b) all possible states.
The Nobel Prize in physics went to Steven Chu, Claude Cohen-Tannoudji, and William Phillips for their development of techniques to slow, stop, and “trap” atoms with laser light. To see how this works, consider a beam of rubidium atoms traveling at after being evaporated out of an oven. A laser beam with a wavelength of is directed against the atoms. This is the wavelength of the transition in rubidium, with being the ground state, so the photons in the laser beam are easily absorbed by the atoms. After an average time of , an excited atom spontaneously emits a wavelength photon and returns to the ground state.
a. The energy-momentum-mass relationship of Einstein’s theory of relativity is . A photon is massless, so the momentum of a photon is . Assume that the atoms are traveling in the positive x-direction and the laser beam in the negative x-direction. What is the initial momentum of an atom leaving the oven? What is the momentum of a photon of light?
b.The total momentum of the atom and the photon must be conserved in the absorption processes. As a consequence, how many photons must be absorbed to bring the atom to a halt?
NOTE Momentum is also conserved in the emission processes. However, spontaneously emitted photons are emitted in random directions. Averaged over many absorption/emission cycles, the net recoil of the atom due to emission is zero and can be ignored.
c. Assume that the laser beam is so intense that a ground-state atom absorbs a photon instantly. How much time is required to stop the atoms?
d. Use Newton’s second law in the form to calculate the force exerted on the atoms by the photons. From this, calculate the atoms’ acceleration as they slow.
e. Over what distance is the beam of atoms brought to a halt?
When all quantum numbers are considered, how many different quantum states are there for a hydrogen atom with? With? With? List the quantum numbers of each state.
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