An electron in a harmonic potential well absorbs a photon with a wavelength of 400nmas it undergoes a 12 quantum jump. What wavelength is absorbed in a 13 quantum jump?

Short Answer

Expert verified

Wavelength absorbed in 12quantum jump = 200nm

Wavelength absorbed in 13quantum jump=200nm

Step by step solution

01

Step 1. Given information

Energy level of harmonic quantum oscillator,

En=n-12hω2π

Here,

n denotes the state,

h=Planck's constant and

ω= classical angular frequency.

02

Step 2. Quantum jump between 1→2

E1=1-12hω2π

=12hω2π

E2=2-12hω2π

=32hω2π

Now,

λphoton,12=hc32hω2π-12hω2π

=hchω2π

=2πcω

2πcω=400nm

πcω=200nm

03

Step 3. Quantum jump between 1→3

E1=12hω2π

E3=3-12hω2π

=52hω2π

λphoton,13=hc52hω2π-12hω2π

=hc42hω2π

=πcω

As found earlier.

πcω=200nm


λphoton,13=200nm

Thus, the wavelength absorbed in13quantum jump =200nm

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