Consider total reflection at an interface between two nonmagnetic media, with
relative refractive index \(n=c_{1} / c_{2}<1\). For angles of incidence
\(\theta_{1}\) exceeding the critical angle of (8.6.42), Snell's law gives
$$
\sin \theta_{2}=\frac{\sin \theta_{1}}{n}>1,
$$
which implies that \(\theta_{2}\) is a complex angle with an imaginary cosine,
$$
\cos \theta_{2}=\left(1-\sin ^{2} \theta_{2}\right)^{1 / 2}=j\left(\frac{\sin
^{2} \theta_{1}}{n^{2}}-1\right)^{1 / 2}
$$
Substitute these relations in the case I reflection coefficient (8.6.28) to
establish
$$
R_{\mathbf{E} \perp}=e^{-i 2 \phi_{\perp}},
$$
where
$$
\tan \phi_{\perp}=\frac{\left(\sin ^{2} \theta_{1}-n^{2}\right)^{1 / x}}{\cos
\theta_{1}}
$$
That is, the magnitude of the reflection coefficient is unity, but the phase
of the reflected wave depends upon angle. Similarly show for case II from
(8.6.36), that \(R_{\text {III }}=e^{-\text {jod with }}\)
$$
\tan \phi \|=\frac{\left(\sin ^{2} \theta_{1}-n^{2}\right)^{1 / 2}}{n^{2} \cos
\theta_{1}}=\frac{1}{n^{2}} \tan \phi_{\perp} .
$$
Note that the two phase shifts are different, so that in general the state of
polarization of an incident wave is altered.