Polarizability is a measure of how easily the electron cloud of an atom or molecule can be distorted. Higher polarizability means that an atom's electrons are more easily shifted, which leads to stronger instantaneous dipoles and thus stronger London dispersion forces.
Several factors influence polarizability:
- Atomic Size: Larger atoms have more easily distorted electron clouds, leading to higher polarizability.
- Number of Electrons: More electrons mean more significant fluctuations, which increases polarizability.
In the context of noble gases, xenon is more polarizable than krypton. This higher polarizability means xenon experiences stronger fluctuating dipole bonds and stronger London dispersion forces.
In summary, larger and more electron-rich atoms tend to be more polarizable, making them more prone to forming stronger dipole interactions.