Chapter 8: Problem 2
Show that the reciprocal lattice for a body centred cubic is a face centred cubic.
Short Answer
Expert verified
The reciprocal lattice of a BCC structure is an FCC lattice.
Step by step solution
01
Understand the Given Structures
A body-centred cubic (BCC) lattice is one where there is a lattice point at each corner of the cube and one at the center. A face-centred cubic (FCC) lattice has lattice points at each corner and the centers of all the faces.
02
Determine the Primitive Vectors for BCC
For a BCC lattice, the conventional unit cell can be defined by the primitive vectors:a1 = (a/2)(x + y - z)a2 = (a/2)(-x + y + z)a3 = (a/2)(x - y + z)where 'a' is the side length of the cubic cell and x, y, z are unit vectors along the respective axes.
03
Reciprocal Lattice Vectors Calculation
From the definition of reciprocal lattice vectors, we have:b1 = 2π (a2 × a3) / (a1 · (a2 × a3))b2 = 2π (a3 × a1) / (a1 · (a2 × a3))b3 = 2π (a1 × a2) / (a1 · (a2 × a3))Substituting the primitive vectors of the BCC, we get:b1 = (2π/a)(y + z)b2 = (2π/a)(z + x)b3 = (2π/a)(x + y)
04
Simplifying Reciprocal Vectors
Simplify the expressions for the reciprocal vectors to see their geometric meaning. The resulting vectors are:b1 = (2π/a)(y + z)b2 = (2π/a)(z + x)b3 = (2π/a)(x + y)These vectors form an FCC structure as they connect the centers of the faces of the cubic cell.
05
Conclusion
Since the primitive vectors of the reciprocal lattice of a BCC structure form an FCC lattice, it is clear that the reciprocal lattice of a body-centered cubic is indeed a face-centered cubic structure.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
body-centred cubic lattice
A body-centred cubic (BCC) lattice is a common crystal structure. Imagine a cube. In this cube, there's a lattice point (or atom) at every corner of the cube. Besides these corner points, there's also an atom right in the center of the cube.
BCC can be visualized as:
BCC can be visualized as:
- Eight atoms at the corners of the cube
- One atom at the center of the cube
face-centred cubic lattice
A face-centred cubic (FCC) lattice is another critical arrangement in crystallography. In this lattice, there are atoms at each corner of the cube and in the center of each face of the cube.
You can think of an FCC lattice as having:
You can think of an FCC lattice as having:
- Eight atoms at the corners of the cube
- Six atoms at the center of each face of the cube
reciprocal lattice vectors
Reciprocal lattices are essential for understanding phenomena like X-ray diffraction. The reciprocal lattice of a crystal lattice simplifies understanding of wave propagation in the lattice. Reciprocal lattice vectors are calculated using the primitive vectors of the direct lattice.
b1 = 2π (a2 × a3) / (a1 · (a2 × a3))
b2 = 2π (a3 × a1) / (a1 · (a2 × a3))
b3 = 2π (a1 × a2) / (a1 · (a2 × a3))
When the calculations are done, you find that the reciprocal lattice of a BCC is an FCC. This shows a direct relationship between the two types of lattices and helps us understand crystal structures much better.
- For a given lattice, we can find primitive vectors (a1, a2, a3).
- The reciprocal lattice vectors (b1, b2, b3) are calculated using these primitive vectors.
b1 = 2π (a2 × a3) / (a1 · (a2 × a3))
b2 = 2π (a3 × a1) / (a1 · (a2 × a3))
b3 = 2π (a1 × a2) / (a1 · (a2 × a3))
When the calculations are done, you find that the reciprocal lattice of a BCC is an FCC. This shows a direct relationship between the two types of lattices and helps us understand crystal structures much better.