On a certain crystal, a first-order X-ray diffraction maximum is observed at an angle of \(27.1^{\circ}\) relative to its surface, using an X-ray source of unknown wavelength. Additionally, when illuminated with a different, this time of known wavelength \(0.137 \mathrm{nm},\) a second-order maximum is detected at \(37.3^{\circ} .\) Determine (a) the spacing between the reflecting planes, and (b) the unknown wavelength.

Short Answer

Expert verified
The spacing between the reflecting planes is approximately 0.235 nm, and the unknown wavelength is approximately 0.207 nm.

Step by step solution

01

Use Bragg's Law with the second-order maximum data

Using Bragg's Law and the given angle and wavelength for the second-order maximum, we can find the spacing between the reflecting planes (d). \(n \lambda = 2d \sin{\theta}\) We are given n = 2, λ = 0.137 nm, and θ = 37.3°. Plug in the values and solve for d: \(2 \times 0.137 \mathrm{nm} = 2d \sin{37.3^{\circ}}\)
02

Solve for the spacing between the reflecting planes (d)

Now, we solve the equation for d by dividing both sides by 2sin(37.3°): \(d = \frac{2 \times 0.137 \mathrm{nm}}{2\sin{37.3^{\circ}}}\) \(d = 0.137 \mathrm{nm} \div \sin{37.3^{\circ}}\) \(d \approx 0.235 \mathrm{nm}\) Thus, we find that the spacing between the reflecting planes is approximately 0.235 nm.
03

Use Bragg's Law with the first-order maximum data

Now, we will use Bragg's Law with the given angle for the first-order maximum and the calculated value of d to find the unknown wavelength (λ). \(n \lambda = 2d \sin{\theta}\) We have n = 1, d = 0.235 nm, and θ = 27.1°. Plug in the values and solve for λ: \(1 \times \lambda = 2 \times 0.235 \mathrm{nm} \sin{27.1^{\circ}}\)
04

Solve for the unknown wavelength (λ)

Now, we solve the equation for λ by dividing both sides by sin(27.1°): \(\lambda = 2 \times 0.235 \mathrm{nm} \div \sin{27.1^{\circ}}\) \(\lambda \approx 0.207 \mathrm{nm}\) Thus, we find that the unknown wavelength is approximately 0.207 nm. In conclusion, the spacing between the reflecting planes is approximately 0.235 nm, and the unknown wavelength is approximately 0.207 nm.

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