Compare orbital angular momentum with spin angular momentum of an electron in the hydrogen atom.

Short Answer

Expert verified
Orbital angular momentum and spin angular momentum, both quantized, arise from different aspects of an electron's behavior. The former is due to the electron’s motion around the nucleus, and its direction is undetermined while the magnitude depends on the azimuthal quantum number. The latter, in contrast, is an intrinsic property of the electron, always with a magnitude of \( \sqrt{3}/2 \hbar \), and can only be up or down in orientation.

Step by step solution

01

Understanding Orbital Angular Momentum

Orbital angular momentum emerges from the motion of the electron around the nucleus. Its magnitude is quantized and given by \( \sqrt{l(l+1) \hbar } \), where l is the azimuthal quantum number and \(\hbar\) is the reduced Planck’s constant. The direction, however, is not completely determined - it's known only that the angular momentum vector points somewhere on a cone.
02

Understanding Spin Angular Momentum

Spin angular momentum, on the other hand, is an intrinsic property of electrons. It's similar to the angular momentum of a spinning particle, although it can't be explained via classical mechanics. The magnitude of spin angular momentum is quantized and given by \( \sqrt{s(s+1) \hbar} \), with s always equalling to 1/2 for electrons (spin quantum number), making its magnitude always equal to \( \sqrt{3}/2 \hbar \). The direction of the spin can be either up or down with respect to an external magnetic field.
03

Comparison

So in comparison, both orbital and spin angular momenta are quantized but the quantization comes from different sources. For orbital, it comes from the restricted motion of the electron (defined by quantized energy levels), while for spin, it's an inherent quantum property of the electron. Moreover, the direction of orbital angular momentum is undetermined while the direction of spin can only be up or down, showing a difference in terms of their orientation properties.

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