Chapter 8: Problem 80
What are the approximate energies of the \(K_{\alpha}\) and \(K_{\beta}\) X-rays for copper?
Short Answer
Expert verified
The approximate energies of the \(K_{\alpha}\) and \(K_{\beta}\) X-rays for copper are:
For \(K_{\alpha}\) X-rays:
\[
E_{\alpha} \approx h \times A(29-1)^{2}(3.29 \times 10^{15} Hz)
\]
For \(K_{\beta}\) X-rays:
\[
E_{\beta} \approx h \times A(29-1)^{2}(3.29 \times 10^{15} Hz)
\]
Step by step solution
01
Determine the atomic number of copper
Copper is a chemical element with the symbol Cu and has an atomic number (Z) of 29.
02
Use Moseley's law to find the frequencies of the K-alpha and K-beta X-rays
For \(K_{\alpha}\) X-rays, the transition is from a shell with quantum number n=2 to the K-shell with quantum number n=1. For \(K_{\beta}\) X-rays, the transition is from a shell with quantum number n=3 to the K-shell with quantum number n=1.
Moseley's law states that the frequency (\(\nu\)) of the characteristic X-ray emitted by an element with an atomic number Z can be given by:
\[
\nu = A(Z-B)^{2}(Ry)
\]
where A is a constant, B is the screening constant (approximately equal to 1 for K-series X-rays), and Ry is the Rydberg constant for hydrogen (\(\approx 3.29 \times 10^{15} Hz\)).
For \(K_{\alpha}\) X-rays, the frequency is:
\[
\nu_{\alpha} = A(29-1)^{2}(3.29 \times 10^{15} Hz)
\]
For \(K_{\beta}\) X-rays, the frequency is:
\[
\nu_{\beta} = A(29-1)^{2}(3.29 \times 10^{15} Hz)
\]
03
Calculate the energies of the K-alpha and K-beta X-rays
The energy of a photon can be calculated using the formula:
\[
E = h\nu
\]
where h is the Planck's constant (\(6.626 \times 10^{-34} Js\)) and \(\nu\) is the frequency of the X-ray.
Substituting the expressions for the \(K_{\alpha}\) and \(K_{\beta}\) X-ray frequencies obtained in step 2, we can calculate their energies as follows:
For \(K_{\alpha}\) X-rays:
\[
E_{\alpha} = h\nu_{\alpha} = h \times A(29-1)^{2}(3.29 \times 10^{15} Hz)
\]
For \(K_{\beta}\) X-rays:
\[
E_{\beta} = h\nu_{\beta} = h \times A(29-1)^{2}(3.29 \times 10^{15} Hz)
\]
After calculating the energies, we can approximate the energies of the \(K_{\alpha}\) and \(K_{\beta}\) X-rays for copper.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Moseley's Law
Moseley's law is a pivotal concept in understanding the behavior of X-rays emitted by elements. English physicist Henry Moseley discovered a relationship between the frequency of X-rays produced by the elements and their atomic numbers. According to this law, the frequency of the X-rays is related to the square of the effective nuclear charge, which accounts for the atomic number (Z) minus the screening constant (B).
For K-series X-rays, the formula is often simplified to \[u = A(Z - B)^{2} \times Ry\]Here, A is a proportionality constant and Ry is the Rydberg constant specifically for hydrogen. The Screening constant B is approximated as 1 for K-series X-rays due to minimal electron screening effect. This law allows us to predict the frequencies of the characteristic X-rays, such as the K-alpha (\(K_{\alpha}\)) and K-beta (\(K_{\beta}\)) transition lines. By knowing the frequency, we can then calculate the energy of these X-rays using Planck's equation.
For K-series X-rays, the formula is often simplified to \[u = A(Z - B)^{2} \times Ry\]Here, A is a proportionality constant and Ry is the Rydberg constant specifically for hydrogen. The Screening constant B is approximated as 1 for K-series X-rays due to minimal electron screening effect. This law allows us to predict the frequencies of the characteristic X-rays, such as the K-alpha (\(K_{\alpha}\)) and K-beta (\(K_{\beta}\)) transition lines. By knowing the frequency, we can then calculate the energy of these X-rays using Planck's equation.
Atomic Number
The atomic number, often denoted by Z, is a fundamental property of an element and is equivalent to the number of protons found in the nucleus of an atom. It uniquely identifies a chemical element and determines its position in the periodic table. The concept of the atomic number is essential in Moseley's law, as it directly affects the emitted X-ray frequencies.
For example, copper has an atomic number of 29. This information allows us to calculate the frequencies and subsequently the energies of the copper K-alpha and K-beta X-rays using Moseley's law. Higher atomic numbers typically result in X-rays with greater frequencies and higher energies, which is a direct consequence of the increased nuclear charge exerted on the electron shells.
For example, copper has an atomic number of 29. This information allows us to calculate the frequencies and subsequently the energies of the copper K-alpha and K-beta X-rays using Moseley's law. Higher atomic numbers typically result in X-rays with greater frequencies and higher energies, which is a direct consequence of the increased nuclear charge exerted on the electron shells.
Photon Energy
Photon energy is the energy carried by a single photon with a certain electromagnetic frequency or wavelength. The energy of a photon is directly proportional to its frequency and inversely proportional to its wavelength. The relationship between energy (E) and frequency (\(u\)) is given by Planck's equation:\[E = hu\]where h is Planck's constant (\(6.626 \times 10^{-34} J\cdot s\)). This fundamental relationship makes it possible to calculate the energy of X-rays after determining their frequencies. For instance, in the step-by-step solution we've seen, after applying Moseley's law to identify the frequencies of copper's K-alpha and K-beta X-rays, we used Planck's equation to calculate their energies, enabling us to understand the level of energy that copper's X-rays possess.
Rydberg Constant
The Rydberg constant is a physical constant related to the atomic spectra of various elements. In the context of Moseley's law, the Rydberg constant for hydrogen (Ry) is often used, with a value of approximately \(3.29 \times 10^{15} Hz\). This constant represents the highest frequency (or smallest wavelength) of any photon that can be emitted by a hydrogen atom, corresponding to a quantum leap from the first excited state to the ground state.
When combined with the appropriate constant (A) and the adjusted atomic number Z (taking into account the electronic screening by subtracting the screening constant B), it allows us to calculate the specific frequencies of the X-rays when electrons transition between energy levels. As a result, the Rydberg constant plays a crucial role in determining the energies of X-rays in various elements, including copper in the provided exercise.
When combined with the appropriate constant (A) and the adjusted atomic number Z (taking into account the electronic screening by subtracting the screening constant B), it allows us to calculate the specific frequencies of the X-rays when electrons transition between energy levels. As a result, the Rydberg constant plays a crucial role in determining the energies of X-rays in various elements, including copper in the provided exercise.