`A pure, defect-free semiconductor material will absorb the electromagnetic
radiation incident on that material only if the energy of the individual
photons in the incident beam is larger than a threshold value known as the
"band-gap" of the semiconductor. The known room-temperature band-gaps for
germanium, silicon, and gallium-arsenide, three widely used semiconductors,
are \(0.66 \mathrm{eV}, 1.12 \mathrm{eV},\) and \(1.42 \mathrm{eV},\)
respectively.
a) Determine the room-temperature transparency range of these semiconductors.
b) Compare these with the transparency range of \(\mathrm{ZnSe}, \mathrm{a}\)
semiconductor with a band-gap of \(2.67 \mathrm{eV},\) and explain the yellow
color observed experimentally for the ZnSe crystals.
c) Which of these materials could be used for a light detector for the 1550
-nm optical communications wavelength?