For a particle trapped in an infinite square well of length \(L\), what happens to the probability that the particle is found between 0 and \(L / 2\) as the particle's energy increases?

Short Answer

Expert verified
Answer: The probability of finding the particle between 0 and L/2 remains constant at 1/2 or 50%, regardless of the energy increase.

Step by step solution

01

The wavefunction of a particle in an infinite square well of length L is given by: $$\psi_n(x) = \sqrt{\frac{2}{L}} \sin\left(\frac{n\pi x}{L}\right),$$ where \(n\) is the quantum number, which is a positive integer \((n = 1, 2, 3, ...)\). #Step 2: Calculate the probability between 0 and L/2#

The probability of finding the particle between \(x=0\) and \(x=L/2\) can be calculated using the Born rule, which states that the probability is given by the integral of the wavefunction squared over the region of interest: $$P_{0 \to L/2}(n) = \int_{0}^{L/2} |\psi_n(x)|^2 dx.$$ Substitute the wavefunction into the integral: $$P_{0 \to L/2}(n)= \int_{0}^{L/2} \left(\sqrt{\frac{2}{L}} \sin\left(\frac{n\pi x}{L}\right)\right)^2 dx.$$ #Step 3: Simplify the expression and find the general result for any n#
02

Simplify the expression by squaring the wavefunction and taking constants out of the integral: $$P_{0 \to L/2}(n) = \frac{2}{L}\int_{0}^{L/2} \sin^2\left(\frac{n\pi x}{L}\right) dx.$$ To solve this integral, we can use the trigonometric identity \(\sin^2(x) = (1 - \cos(2x))/2\): $$P_{0 \to L/2}(n) = \frac{1}{L}\int_{0}^{L/2} \left[1 - \cos\left(\frac{2n\pi x}{L}\right)\right] dx.$$ Now, we can calculate the integral: $$P_{0 \to L/2}(n) = \frac{1}{L}\left[x - \frac{L}{2n\pi} \sin\left(\frac{2n\pi x}{L}\right)\right]_{0}^{L/2}.$$ Evaluate the definite integral: $$P_{0 \to L/2}(n) = \frac{1}{L}\left(\frac{L}{2} - \frac{L}{2n\pi} \sin\left(n\pi\right)\right) - 0.$$ #Step 4: Analyze the result as the energy increases#

We know that the energy of the particle is given by the formula \(E_n = \frac{n^2\pi^2\hbar^2}{2mL^2}\), where \(m\) is the mass of the particle and \(\hbar\) is the reduced Planck constant. Therefore, as energy increases, the quantum number \(n\) also increases. Now let's analyze the probability expression as \(n\) increases: $$P_{0 \to L/2}(n) = \frac{1}{L}\left(\frac{L}{2} - \frac{L}{2n\pi} \sin\left(n\pi\right)\right).$$ As we can observe from the above expression, the term \(\sin(n\pi)\) is always equal to 0 for any positive integer value of \(n\). Thus, the probability simplifies as: $$P_{0 \to L/2}(n) = \frac{1}{L}\left(\frac{L}{2}\right) = \frac{1}{2}.$$ This result implies that regardless of the energy (or the value of \(n\)), the probability of finding the particle between 0 and \(L/2\) remains constant at 1/2 or 50%.

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