Hydrogen atoms are bombarded with 13.1-eV electrons. Determine the shortest wavelength line the atom will emit.

Short Answer

Expert verified
Answer: The shortest wavelength line is 121.6 nm.

Step by step solution

01

Calculate the Energy of an Electron

First, we need to convert the energy of the electron in electron volts (eV) to Joules (J) using the relation 1 eV = 1.6 x 10^-19 J. This will allow us to have the energy in a more convenient unit for the calculations. Energy of electron in eV = 13.1 eV Energy of electron in Joules (J) = 13.1 eV * (1.6 * 10^-19 J/eV) = 2.096 x 10^-18 J.
02

Calculate the Maximum Change in Energy Levels

Since we need to find the shortest wavelength, we need to consider the maximum change in energy levels. The initial energy level (n_initial) is given by the energy of the bombarded electron. The hydrogen atom energy levels are given by the Rydberg formula: E_n = -13.6 eV/n^2, where E_n is the energy of the level n. Now we need to determine the highest possible energy level (n_final) when the electron absorbs the bombarded electron's energy. E_final = E_initial + 13.1 eV, where E_initial = -13.6 eV/n_initial^2, and E_final = -13.6 eV/n_final^2.
03

Solve for the Initial and Final Energy Levels

Solve the equation for n_final in terms of n_initial: -13.6 eV/n_final^2 = -13.6 eV/n_initial^2 + 13.1 eV. Now, we need to find the values of n_initial and n_final for which the energy difference is the highest: max[(-13.6 eV/n_initial^2) - (-13.6 eV/n_final^2)] = 13.1 eV, by using trial and error, we find n_initial = 1 and n_final = 3.
04

Calculate the Wavelength using the Rydberg Formula

Now that we have the initial and final energy levels, we can use the Rydberg formula for the hydrogen atom to calculate the wavelength: 1/λ = R_H * (1/n_initial^2 - 1/n_final^2), where λ is the wavelength and R_H is the Rydberg constant for hydrogen (1.097 x 10^7 m^-1). Plug in the values for n_initial = 1 and n_final = 3: 1/λ = 1.097 x 10^7 m^-1 * (1/1^2 - 1/3^2) = 1.097 x 10^7 m^-1 * (1 - 1/9) = 1.097 x 10^7 m^-1 * (8/9).
05

Calculate the Shortest Wavelength

Finally, calculate the shortest wavelength: λ = 1 / [1.097 x 10^7 m^-1 * (8/9)] = 1.216 x 10^-7 m. Hence, the shortest wavelength line that the hydrogen atom will emit when bombarded by 13.1-eV electrons is 1.216 x 10^-7 m or 121.6 nm.

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