What is the shortest possible wavelength of the Lyman series in hydrogen?

Short Answer

Expert verified
Answer: The shortest possible wavelength of the Lyman series in hydrogen is approximately 91.1 nm.

Step by step solution

01

Recall the formula for the hydrogen spectral lines

To calculate the wavelength of the spectral lines in hydrogen, we will use the Rydberg formula for hydrogen: $$\frac{1}{\lambda} = R_H \left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right)$$ In this formula, λ represents the wavelength, 𝑅_H is the Rydberg constant for hydrogen (approximately 1.097 x 10^7 m⁻¹), n₁ and n₂ are the principal quantum numbers of the initial and final energy levels, respectively.
02

Determine n₁ and n₂ for the Lyman series

For the Lyman series, electron transitions occur between the first energy level (n = 1) and any higher energy level (n > 1). To find the shortest wavelength, we need the transition with the highest energy difference, which corresponds to an electron transitioning from n -> infinity (n₂ = ∞) to the first energy level (n₁ = 1).
03

Plug the values into the Rydberg formula

Now that we have n₁ = 1 and n₂ = ∞, we can plug these values into the Rydberg formula: $$\frac{1}{\lambda} = R_H \left(\frac{1}{1^2} - \frac{1}{\infty^2}\right)$$
04

Simplify the equation

Now, simplifying the equation, we get: $$\frac{1}{\lambda} = R_H (1 - 0)$$ $$\frac{1}{\lambda} = R_H$$
05

Find the shortest possible wavelength

Now, we can solve for λ by taking the reciprocal of both sides of the equation: $$\lambda = \frac{1}{R_H}$$ Plugging in the value of 𝑅_H (1.097 x 10^7 m⁻¹): $$\lambda = \frac{1}{1.097 \times 10^7 \mathrm{m^{-1}}}$$ Thus, the shortest possible wavelength of the Lyman series in hydrogen is: $$\lambda ≈ 9.11 \times 10^{-8} \mathrm{m}$$ or approximately 91.1 nm.

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