
In the loop 1st the current equation according to the Kirchhoff’s law,
\(\begin{aligned}1{\rm{2V}} - I\left( {1.00\Omega + 2.00\Omega + 2.00\Omega + 1.00\Omega } \right) - 8.{\rm{0V}} - I\left( {2.00\Omega + 1.00\Omega } \right) = 0\\I = \frac{{12.0V - 8.0V}}{{9.00\Omega }}\\I = 0.4444{\rm{A}}\end{aligned}\)
Now to calculate the voltage between a add b we have to start from point b to a that is loop 2, so now,
\(\begin{aligned}{V_b} - 10{\rm{V + 12V}} - 0.4444{\rm{A}}\left( {1.00\Omega + 1.00\Omega + 2.00\Omega } \right) = {V_a}\\{V_a} - {V_b} = + 0.22{\rm{V}}\end{aligned}\)
It is showing potential a is at higher potential,
Hence, the potential of point a with respect to point b is \({V_a} - {V_b} = + 0.22{\rm{V}}\).