The gas used in separating the two uranium isotopesU235andU238have the formulaUF6. If you added heat at equal rates to a mole ofUF6gas and a mole ofH2gas, which one’s temperature would you expect to rise faster? Explain.

Short Answer

Expert verified

The temperature ofH2 rises faster thanUF6 because it has less degree of freedom.

Step by step solution

01

Understanding the degree of freedom

It measures a specific number of ways the particular molecule moves, like rotation, molecules’s vibration, and translation. This quantity describes the state of any system.

02

Determination of the molecule’s temperature would expect to rise faster

TheUF6molecule has many more internal degrees of freedom (rotation, vibration) thanH2does.

Therefore, more heat is required for a given temperature change inUF6 thanH2 , because forUF6a larger fraction heat added goes into the internal motions of the molecule and less into the translation motion that determines the temperature.

Said another way,Cv the polyatomic moleculeUF6 is larger thanCv (diatomic molecule), so a given amount of heat flowing into the gas gives a smaller temperature rise inUF6 .

Hence, the temperature of H2rises faster thandata-custom-editor="chemistry" UF6 because it has less degree of freedom.

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